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- W2921844146 abstract "Abstract Iron‐based metal organic framework (MOF) MIL‐53 is used as a precursor and self‐template to synthesize a 3D porous carbon/FeF 3 ⋅ 0.33 H 2 O composite in situ. We find that the organic ligands in iron‐containing MOFs can convert into highly graphitized carbon with the catalysis of central Fe atoms. The FeF 3 ⋅ 0.33 H 2 O nanoparticles formed after fluorination and dehydration are surrounded by highly graphitized carbon. In the composite, the graphitized 3D porous carbon can provide passageways for electron transport and ultrasmall FeF 3 ⋅ 0.33 H 2 O nanoparticles facilitate the diffusion of Li ions. The composite shows excellent performance for the Li storage. A capacity of 86 mAh g −1 can be reached at an ultra‐high rate of 20 C. Even after 300 charge−discharge cycles at 5 C, the capacity remains at 113 mAh g −1 ." @default.
- W2921844146 created "2019-03-22" @default.
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- W2921844146 date "2019-03-20" @default.
- W2921844146 modified "2023-10-15" @default.
- W2921844146 title "Ultrasmall Iron Fluoride Nanoparticles Embedded in Graphitized Porous Carbon Derived from Fe‐Based Metal Organic Frameworks as High‐Performance Cathode Materials for Li Batteries" @default.
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- W2921844146 doi "https://doi.org/10.1002/celc.201900244" @default.
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