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- W2922150020 abstract "The facile synthesis of functionalized azetidines has been an ongoing challenge. Here, we report a general method to directly alkylate 1-azabicyclo[1.1.0]butane (ABB) with organometal reagents in the presence of Cu(OTf)2 to rapidly prepare bis-functionalized azetidines. This method allows for the preparation of azetidines bearing alkyl, allyl, vinyl, and benzyl groups. This catalyst system was extended to aziridines and spirocycles. Several building blocks and drug-like compounds were prepared in rapid fashion and in good yield." @default.
- W2922150020 created "2019-03-22" @default.
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- W2922150020 creator A5081096539 @default.
- W2922150020 date "2019-03-11" @default.
- W2922150020 modified "2023-10-18" @default.
- W2922150020 title "Direct Alkylation of 1-Azabicyclo[1.1.0]butanes" @default.
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- W2922150020 doi "https://doi.org/10.1021/acs.orglett.9b00321" @default.
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