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- W2922157904 abstract "In this study, we report a superior dehydrogenation catalyst for dimethylamine borane, which exhibited one of the best catalytic activities. The newly formed catalyst system contains well dispersed ruthenium-copper nanomaterials on reduced graphene oxide (3.86 ± 0.47 nm), which was prepared by using the ultrasonic double reduction technique. The characterization of monodisperse ruthenium-copper alloy nanoparticles was performed using some advanced analytical methods such as TEM, HRTEM, XPS, Raman spectroscopic analysis. The experiments results revealed that the monodisperse ruthenium-copper alloy catalyst ([email protected]) has one of the highest catalytic activity compared to previous studies, having a high turnover frequency value (256.70 h−1). The detailed kinetic parameters such as activation energy, enthalpy, and entropy values were also calculated for the dehydrogenation of dimethylamine borane at room temperature. Also, the results showed that the monodisperse [email protected] catalyst has high durability and reusability as retained its 81% initial catalytic activity even after 4th runs for the dehydrogenation of dimethylamine borane." @default.
- W2922157904 created "2019-03-22" @default.
- W2922157904 creator A5009814689 @default.
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- W2922157904 date "2019-04-01" @default.
- W2922157904 modified "2023-10-05" @default.
- W2922157904 title "Monodisperse ruthenium copper alloy nanoparticles decorated on reduced graphene oxide for dehydrogenation of DMAB" @default.
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- W2922157904 doi "https://doi.org/10.1016/j.ijhydene.2019.02.176" @default.
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