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- W2922274803 abstract "The in situ generation of a “cyano” unit from readily available organic precursors is of high interest in synthetic chemistry. Herein, we report the first example of Ni-mediated dehydration of formamide to form “CN” and its subsequent catalytic applications in the hydrocyanation of alkynes and cyanation of aryl halides. Formamide can serve as a convenient source for the nitrile unit, in that it releases water as the only byproduct." @default.
- W2922274803 created "2019-03-22" @default.
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- W2922274803 date "2019-03-14" @default.
- W2922274803 modified "2023-09-29" @default.
- W2922274803 title "Ni-Mediated Generation of “CN” Unit from Formamide and Its Catalysis in the Cyanation Reactions" @default.
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- W2922274803 doi "https://doi.org/10.1021/acscatal.8b05111" @default.
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