Matches in SemOpenAlex for { <https://semopenalex.org/work/W2922286624> ?p ?o ?g. }
- W2922286624 endingPage "282" @default.
- W2922286624 startingPage "253" @default.
- W2922286624 abstract "Noncovalent interactions play an important role in enzyme catalysis, helping to stabilize transition states. Favourable interactions, including hydrogen bonding, π-stacking, CH⋯π and lone pair⋯π interactions, amongst others, may also be responsible for the regioselectivity and high degrees of stereoselectivity that can be achieved with some small-molecule catalysts. Noncovalent interactions often compete with steric effects and identifying and understanding them is not always straightforward. Nevertheless, this can provide a basis for the rational design of new catalysts, to be applied in the synthesis of single enantiomers needed for various applications ranging from pharmaceuticals to advanced materials. This chapter provides an overview of recent findings in the area of chiral phosphoric acid-catalysed reactions. It considers the types of reactions and the modes of activation possible, the models used to predict stereoselectivity and the types of interactions involved. A few case studies selected from the recent literature illustrate the state-of-the-art in this important branch of catalysis." @default.
- W2922286624 created "2019-03-22" @default.
- W2922286624 creator A5027464254 @default.
- W2922286624 date "2019-03-18" @default.
- W2922286624 modified "2023-09-25" @default.
- W2922286624 title "Noncovalent Interactions in Asymmetric Reactions Catalysed by Chiral Phosphoric Acids" @default.
- W2922286624 cites W1966912785 @default.
- W2922286624 cites W1969031477 @default.
- W2922286624 cites W1969514778 @default.
- W2922286624 cites W1969885133 @default.
- W2922286624 cites W1985767466 @default.
- W2922286624 cites W1990566970 @default.
- W2922286624 cites W1996681043 @default.
- W2922286624 cites W1998081397 @default.
- W2922286624 cites W1998677005 @default.
- W2922286624 cites W2004224330 @default.
- W2922286624 cites W2012846252 @default.
- W2922286624 cites W2016075951 @default.
- W2922286624 cites W2017501250 @default.
- W2922286624 cites W2021794341 @default.
- W2922286624 cites W2028356410 @default.
- W2922286624 cites W2044828385 @default.
- W2922286624 cites W2059246929 @default.
- W2922286624 cites W2075332038 @default.
- W2922286624 cites W2079821320 @default.
- W2922286624 cites W2081025937 @default.
- W2922286624 cites W2081839616 @default.
- W2922286624 cites W2085351645 @default.
- W2922286624 cites W2094745278 @default.
- W2922286624 cites W2106336511 @default.
- W2922286624 cites W2114745719 @default.
- W2922286624 cites W2123540673 @default.
- W2922286624 cites W2124923400 @default.
- W2922286624 cites W2129130563 @default.
- W2922286624 cites W2129462844 @default.
- W2922286624 cites W2134019393 @default.
- W2922286624 cites W2143086715 @default.
- W2922286624 cites W2143729242 @default.
- W2922286624 cites W2150796935 @default.
- W2922286624 cites W2150865621 @default.
- W2922286624 cites W2167137322 @default.
- W2922286624 cites W2169174125 @default.
- W2922286624 cites W2170676330 @default.
- W2922286624 cites W2216567860 @default.
- W2922286624 cites W2330263970 @default.
- W2922286624 cites W2331335689 @default.
- W2922286624 cites W2333999978 @default.
- W2922286624 cites W2339250494 @default.
- W2922286624 cites W2343118341 @default.
- W2922286624 cites W2343699080 @default.
- W2922286624 cites W2345159345 @default.
- W2922286624 cites W2405738831 @default.
- W2922286624 cites W2422341232 @default.
- W2922286624 cites W2519805142 @default.
- W2922286624 cites W2520095744 @default.
- W2922286624 cites W2588380691 @default.
- W2922286624 cites W2599634799 @default.
- W2922286624 cites W2601109746 @default.
- W2922286624 cites W2606519374 @default.
- W2922286624 cites W2743567717 @default.
- W2922286624 cites W2756100568 @default.
- W2922286624 cites W2784837692 @default.
- W2922286624 cites W2805383838 @default.
- W2922286624 cites W3047756042 @default.
- W2922286624 cites W4255210206 @default.
- W2922286624 cites W4255422539 @default.
- W2922286624 doi "https://doi.org/10.1039/9781788016490-00253" @default.
- W2922286624 hasPublicationYear "2019" @default.
- W2922286624 type Work @default.
- W2922286624 sameAs 2922286624 @default.
- W2922286624 citedByCount "0" @default.
- W2922286624 crossrefType "book-chapter" @default.
- W2922286624 hasAuthorship W2922286624A5027464254 @default.
- W2922286624 hasConcept C112887158 @default.
- W2922286624 hasConcept C121332964 @default.
- W2922286624 hasConcept C124668440 @default.
- W2922286624 hasConcept C137277065 @default.
- W2922286624 hasConcept C146686406 @default.
- W2922286624 hasConcept C147597530 @default.
- W2922286624 hasConcept C161790260 @default.
- W2922286624 hasConcept C178790620 @default.
- W2922286624 hasConcept C181647583 @default.
- W2922286624 hasConcept C185592680 @default.
- W2922286624 hasConcept C201194858 @default.
- W2922286624 hasConcept C20621625 @default.
- W2922286624 hasConcept C21951064 @default.
- W2922286624 hasConcept C32909587 @default.
- W2922286624 hasConcept C33347731 @default.
- W2922286624 hasConcept C46000676 @default.
- W2922286624 hasConcept C486523 @default.
- W2922286624 hasConcept C52703039 @default.
- W2922286624 hasConcept C59759590 @default.
- W2922286624 hasConcept C62520636 @default.
- W2922286624 hasConcept C66972969 @default.
- W2922286624 hasConcept C71240020 @default.
- W2922286624 hasConcept C7602139 @default.
- W2922286624 hasConceptScore W2922286624C112887158 @default.
- W2922286624 hasConceptScore W2922286624C121332964 @default.