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- W2922384613 abstract "Presented herein is an intriguing effect of fluorine, and it allows difluoroenol silyl ethers to couple with aryliodanes in a redox-neutral manner to afford ortho-iodo difluoroalkylated arenes. The remaining iodide group provides a versatile platform for converting the products into various valuable difluoroalkylated arenes. The reaction shows excellent functional-group compatibility and broad substrate scope. A DFT mechanistic study suggests that the fluorine effect facilitates a subtle nucleophilic attack of the oxygen atom of enol silyl ethers onto aryliodanes, therefore leading to a rearrangement." @default.
- W2922384613 created "2019-03-22" @default.
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- W2922384613 date "2019-04-23" @default.
- W2922384613 modified "2023-10-16" @default.
- W2922384613 title "The <i>ortho</i> ‐Difluoroalkylation of Aryliodanes with Enol Silyl Ethers: Rearrangement Enabled by a Fluorine Effect" @default.
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- W2922384613 doi "https://doi.org/10.1002/anie.201900745" @default.
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