Matches in SemOpenAlex for { <https://semopenalex.org/work/W2922389516> ?p ?o ?g. }
- W2922389516 endingPage "3197" @default.
- W2922389516 startingPage "3188" @default.
- W2922389516 abstract "The syntheses and characterisation of the first ten homologues of the 1-(4-cyanobiphenyl-4'-yl)-6-(4-alkylanilinebenzylidene-4'-oxy)hexanes (CB6O.m) are reported. All ten members of the series exhibit an enantiotropic nematic, N, phase, and a monotropic twist-bend nematic, NTB, phase. Only CB6O.10 shows a smectic phase. The assignment of both nematic phases was confirmed using X-ray diffraction. For short chain lengths (m = 1-6) the local packing in both nematic phases is an intercalated arrangement, for intermediate chain lengths a frustrated local structure is seen and for the longest chain length, a bilayer arrangement is observed. This change in the local structure on increasing m has no apparent effect on the stability of either nematic phase, and TNTBN and TNI show a regular dependence on m. Specifically, TNTBN and TNI decrease on increasing m and superimposed upon this is a weak odd-even effect in which the odd members show the higher values. TNI decreases more rapidly than TNTBN on increasing m such that the ratio TNTBN/TNI increases. The lower temperature liquid crystal phase shown by 1-(4-cyanobiphenyl-4'-yloxy)-5-(4-butylanilinebenzylidene-4'-oxy)pentane (CBO5O.4) is reassigned as a twist-bend nematic phase. The transitional properties of the CB6O.m, CB6O.Om and CBO5O.m series are compared." @default.
- W2922389516 created "2019-03-22" @default.
- W2922389516 creator A5039237652 @default.
- W2922389516 creator A5043257240 @default.
- W2922389516 creator A5055344298 @default.
- W2922389516 creator A5060658536 @default.
- W2922389516 creator A5068567685 @default.
- W2922389516 creator A5075085575 @default.
- W2922389516 date "2019-01-01" @default.
- W2922389516 modified "2023-10-16" @default.
- W2922389516 title "Molecular curvature, specific intermolecular interactions and the twist-bend nematic phase: the synthesis and characterisation of the 1-(4-cyanobiphenyl-4′-yl)-6-(4-alkylanilinebenzylidene-4′-oxy)hexanes (CB6O.<i>m</i>)" @default.
- W2922389516 cites W1935116657 @default.
- W2922389516 cites W1942260081 @default.
- W2922389516 cites W1966433434 @default.
- W2922389516 cites W1970138636 @default.
- W2922389516 cites W1973209606 @default.
- W2922389516 cites W1975265489 @default.
- W2922389516 cites W1976040867 @default.
- W2922389516 cites W1976662532 @default.
- W2922389516 cites W1989931206 @default.
- W2922389516 cites W2010885817 @default.
- W2922389516 cites W2017956517 @default.
- W2922389516 cites W2021665432 @default.
- W2922389516 cites W2031822273 @default.
- W2922389516 cites W2040315761 @default.
- W2922389516 cites W2044014486 @default.
- W2922389516 cites W2047787167 @default.
- W2922389516 cites W2052891955 @default.
- W2922389516 cites W2056261353 @default.
- W2922389516 cites W2060513722 @default.
- W2922389516 cites W2063644787 @default.
- W2922389516 cites W2064861328 @default.
- W2922389516 cites W2072556422 @default.
- W2922389516 cites W2077602060 @default.
- W2922389516 cites W2084202796 @default.
- W2922389516 cites W2133716769 @default.
- W2922389516 cites W2134335456 @default.
- W2922389516 cites W2154069299 @default.
- W2922389516 cites W2160216942 @default.
- W2922389516 cites W2164986859 @default.
- W2922389516 cites W2168027258 @default.
- W2922389516 cites W2174827058 @default.
- W2922389516 cites W2225984143 @default.
- W2922389516 cites W2275242636 @default.
- W2922389516 cites W2308279817 @default.
- W2922389516 cites W2310430933 @default.
- W2922389516 cites W2331388644 @default.
- W2922389516 cites W2347114314 @default.
- W2922389516 cites W2411157226 @default.
- W2922389516 cites W2468348741 @default.
- W2922389516 cites W2471809395 @default.
- W2922389516 cites W2518203840 @default.
- W2922389516 cites W2532811421 @default.
- W2922389516 cites W2543504006 @default.
- W2922389516 cites W2548720942 @default.
- W2922389516 cites W2789447238 @default.
- W2922389516 cites W2789970281 @default.
- W2922389516 cites W2793824200 @default.
- W2922389516 cites W2802569912 @default.
- W2922389516 cites W2811316989 @default.
- W2922389516 cites W2891542236 @default.
- W2922389516 cites W2897411699 @default.
- W2922389516 cites W3104014869 @default.
- W2922389516 cites W4248758138 @default.
- W2922389516 doi "https://doi.org/10.1039/c9sm00026g" @default.
- W2922389516 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30892369" @default.
- W2922389516 hasPublicationYear "2019" @default.
- W2922389516 type Work @default.
- W2922389516 sameAs 2922389516 @default.
- W2922389516 citedByCount "69" @default.
- W2922389516 countsByYear W29223895162019 @default.
- W2922389516 countsByYear W29223895162020 @default.
- W2922389516 countsByYear W29223895162021 @default.
- W2922389516 countsByYear W29223895162022 @default.
- W2922389516 countsByYear W29223895162023 @default.
- W2922389516 crossrefType "journal-article" @default.
- W2922389516 hasAuthorship W2922389516A5039237652 @default.
- W2922389516 hasAuthorship W2922389516A5043257240 @default.
- W2922389516 hasAuthorship W2922389516A5055344298 @default.
- W2922389516 hasAuthorship W2922389516A5060658536 @default.
- W2922389516 hasAuthorship W2922389516A5068567685 @default.
- W2922389516 hasAuthorship W2922389516A5075085575 @default.
- W2922389516 hasBestOaLocation W29223895162 @default.
- W2922389516 hasConcept C13274807 @default.
- W2922389516 hasConcept C166950319 @default.
- W2922389516 hasConcept C178790620 @default.
- W2922389516 hasConcept C185592680 @default.
- W2922389516 hasConcept C192157962 @default.
- W2922389516 hasConcept C192562407 @default.
- W2922389516 hasConcept C195065555 @default.
- W2922389516 hasConcept C2524010 @default.
- W2922389516 hasConcept C2776196297 @default.
- W2922389516 hasConcept C32909587 @default.
- W2922389516 hasConcept C33923547 @default.
- W2922389516 hasConcept C41625074 @default.
- W2922389516 hasConcept C44280652 @default.
- W2922389516 hasConcept C49040817 @default.
- W2922389516 hasConcept C55493867 @default.