FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2922754416> ?p ?o ?g. }

• W2922754416 endingPage "2311" @default.
• W2922754416 startingPage "2304" @default.
• W2922754416 abstract "The mixed‐valence europium tantalum nitride oxide Eu II Eu III 2 Ta 2 N 4 O 3 was synthesized with the ammonothermal approach in high‐pressure custom‐built autoclaves. The reaction was performed at 1070 K and a maximum pressure of 170 MPa in an ammonobasic environment with NaN 3 and NaOH as mineralizers. Eu II Eu III 2 Ta 2 N 4 O 3 was obtained as a black microcrystalline powder. Single‐crystal synchrotron diffraction data revealed a Ruddlesden‐Popper phase crystallizing in space group P 4 2 / mnm (no. 136) with a = 5.7278(1), c = 19.8149(5) Å and Z = 4. The crystallographic results from single‐crystal diffraction data have been confirmed by powder diffraction and TEM measurements. Anion positions were assigned to O and N based on bond‐valence (BVS), lattice energy (MAPLE) and charge distribution calculations (CHARDI). Eu II and Eu III are crystallographically ordered. The band gap was estimated from UV/Vis measurements employing the Kubelka–Munk function to be 0.6 eV, which supports the black color and the mixed valence of europium." @default.
• W2922754416 created "2019-04-01" @default.
• W2922754416 creator A5021142344 @default.
• W2922754416 creator A5022595225 @default.
• W2922754416 creator A5025312248 @default.
• W2922754416 creator A5031152558 @default.
• W2922754416 creator A5064563706 @default.
• W2922754416 date "2019-04-12" @default.
• W2922754416 modified "2023-10-17" @default.
• W2922754416 title "Ammonothermal Synthesis of the Mixed‐Valence Nitrogen‐Rich Europium Tantalum Ruddlesden‐Popper Phase Eu^IIEu^III₂Ta₂N₄O₃" @default.
• W2922754416 cites W101015286 @default.
• W2922754416 cites W1550455602 @default.
• W2922754416 cites W1593692683 @default.
• W2922754416 cites W1647960007 @default.
• W2922754416 cites W1806390784 @default.
• W2922754416 cites W1883417833 @default.
• W2922754416 cites W1896101600 @default.
• W2922754416 cites W1939960297 @default.
• W2922754416 cites W1963718260 @default.
• W2922754416 cites W1969360633 @default.
• W2922754416 cites W1969638099 @default.
• W2922754416 cites W1973434229 @default.
• W2922754416 cites W1973838994 @default.
• W2922754416 cites W1986190632 @default.
• W2922754416 cites W1988692840 @default.
• W2922754416 cites W1989070073 @default.
• W2922754416 cites W1998825948 @default.
• W2922754416 cites W2003933418 @default.
• W2922754416 cites W2015480166 @default.
• W2922754416 cites W2018701435 @default.
• W2922754416 cites W2028056984 @default.
• W2922754416 cites W2040875144 @default.
• W2922754416 cites W2042047863 @default.
• W2922754416 cites W2042628264 @default.
• W2922754416 cites W2046003679 @default.
• W2922754416 cites W2046329572 @default.
• W2922754416 cites W2046830341 @default.
• W2922754416 cites W2049986789 @default.
• W2922754416 cites W2050429372 @default.
• W2922754416 cites W2051811025 @default.
• W2922754416 cites W2053671000 @default.
• W2922754416 cites W2054364415 @default.
• W2922754416 cites W2057145778 @default.
• W2922754416 cites W2066987154 @default.
• W2922754416 cites W2068706736 @default.
• W2922754416 cites W2074019256 @default.
• W2922754416 cites W2079297914 @default.
• W2922754416 cites W2081754528 @default.
• W2922754416 cites W2088765014 @default.
• W2922754416 cites W2093331632 @default.
• W2922754416 cites W2093633598 @default.
• W2922754416 cites W2100522043 @default.
• W2922754416 cites W2101741054 @default.
• W2922754416 cites W2114911094 @default.
• W2922754416 cites W2117685850 @default.
• W2922754416 cites W2136260243 @default.
• W2922754416 cites W2144089653 @default.
• W2922754416 cites W2152638761 @default.
• W2922754416 cites W2155176366 @default.
• W2922754416 cites W2158063974 @default.
• W2922754416 cites W2167071112 @default.
• W2922754416 cites W2167590372 @default.
• W2922754416 cites W2269427755 @default.
• W2922754416 cites W2328465982 @default.
• W2922754416 cites W2507764909 @default.
• W2922754416 cites W2517145519 @default.
• W2922754416 cites W2559462292 @default.
• W2922754416 cites W2606230247 @default.
• W2922754416 cites W2728604607 @default.
• W2922754416 cites W2740048161 @default.
• W2922754416 cites W2742245680 @default.
• W2922754416 cites W2757985217 @default.
• W2922754416 cites W2760313273 @default.
• W2922754416 cites W2766151058 @default.
• W2922754416 cites W2766763801 @default.
• W2922754416 cites W2774567265 @default.
• W2922754416 cites W2789382402 @default.
• W2922754416 cites W2789882058 @default.
• W2922754416 cites W2790632347 @default.
• W2922754416 cites W2793239025 @default.
• W2922754416 cites W2793386518 @default.
• W2922754416 cites W2793437119 @default.
• W2922754416 cites W2810086552 @default.
• W2922754416 cites W2810294479 @default.
• W2922754416 cites W2883417956 @default.
• W2922754416 cites W2884355231 @default.
• W2922754416 cites W2898230818 @default.
• W2922754416 cites W2949170833 @default.
• W2922754416 cites W2949481870 @default.
• W2922754416 cites W2949560946 @default.
• W2922754416 cites W2949801637 @default.
• W2922754416 cites W2951781060 @default.
• W2922754416 cites W2951938335 @default.
• W2922754416 cites W4234203492 @default.
• W2922754416 cites W4243035698 @default.
• W2922754416 cites W79039224 @default.
• W2922754416 doi "https://doi.org/10.1002/ejic.201900245" @default.
• W2922754416 hasPublicationYear "2019" @default.

• next