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- W2922801381 abstract "Tailored ruthenium(IV) complexes can catalyze the isomerization of allylic alcohols into saturated carbonyl derivatives under physiologically relevant conditions, and even inside living mammalian cells. The reaction, which involves ruthenium-hydride intermediates, is bioorthogonal and biocompatible, and can be used for the in cellulo generation of fluorescent and bioactive probes. Overall, our research reveals a novel metal-based tool for cellular intervention, and comes to further demonstrate the compatibility of organometallic mechanisms with the complex environment of cells." @default.
- W2922801381 created "2019-04-01" @default.
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- W2922801381 date "2019-03-20" @default.
- W2922801381 modified "2023-10-16" @default.
- W2922801381 title "Ruthenium-Catalyzed Redox Isomerizations inside Living Cells" @default.
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- W2922801381 doi "https://doi.org/10.1021/jacs.9b00837" @default.
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