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• W2922803559 endingPage "2289" @default.
• W2922803559 startingPage "2285" @default.
• W2922803559 abstract "A cobalt-catalyzed cross-coupling between alkyl iodides and cyclopropyl, cyclobutyl, and alkenyl Grignard reagents is disclosed. The reaction allows the introduction of strained rings on a large panel of primary and secondary alkyl iodides. The catalytic system is simple and nonexpensive, and the reaction is general, chemoselective, and diastereoconvergent. The alkene resulting from the cross-coupling can be transformed to substituted cyclopropanes using a Simmons–Smith reaction. The formation of radical intermediates during the coupling is hypothesized." @default.
• W2922803559 created "2019-04-01" @default.
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• W2922803559 date "2019-03-21" @default.
• W2922803559 modified "2023-10-09" @default.
• W2922803559 title "Introduction of Cyclopropyl and Cyclobutyl Ring on Alkyl Iodides through Cobalt-Catalyzed Cross-Coupling" @default.
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• W2922803559 doi "https://doi.org/10.1021/acs.orglett.9b00579" @default.
• W2922803559 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30896173" @default.
• W2922803559 hasPublicationYear "2019" @default.
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