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• W2922865154 abstract "A highly sensitive and selective optical membrane for determination of Au3+ was synthesized by immobilization of a rhodamine derivative on agarose hydrogel. The sensing dye was synthesized by solvatochromism of rhodamine B via rhodamine lactone-zwitterion equilibrium. UV-vis spectroscopy, scanning electron microscopy (SEM), thermal gravimetric analysis (TGA) and attenuated total reflectance Fourier transform infrared spectroscopy (ATR-FTIR) were employed to confirm that the rhodamine-lactone (RhoL) was incorporated into the agarose hydrogel. The results showed that the sensor was highly selective for recognizing Au3+ over other metal ions in real systems. In addition, DFT calculation results suggested that the membrane sensor formed stable complexes with Au3+ through a large number of cation-dipole and ion-ion interactions. In addition, according to changes in signaling upon adding various Au3+ concentration, the limit of detection of Arg-RhoL for Au3+ is calculated to be 5 µM. This approach may provide an easily measurable and inherently sensitive method for Au3+ ion detection in environmental and biological applications." @default.
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• W2922865154 date "2019-04-04" @default.
• W2922865154 modified "2023-09-23" @default.
• W2922865154 title "Gold sensing with rhodamine immobilized hydrogel-based colorimetric sensor" @default.
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• W2922865154 doi "https://doi.org/10.1080/09593330.2019.1595163" @default.
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