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- W2922876987 abstract "Three types of carbon nanofibers (pyrolytically stripped carbon nanofibers (PS), low-temperature heat treated carbon nanofibers (LHT), and high-temperature heat treated carbon nanofibers (HHT)) with different graphitization degrees and surface chemistry have been used as support for Au, Pd, or bimetallic AuPd alloy nanoparticles (NPs). The carbon supports have been characterized using Raman, X-ray photoelectron spectroscopy (XPS), and cyclic voltammetry (CV). Moreover, the morphology of the metal nanoparticles was investigated using transmission electron microscopy (TEM) and CV. The different properties of the carbon-based supports (particularly the graphitization degree) yield different electrochemical behaviors, in terms of potential window widths and electrocatalytic effects. Comparing the electrochemical behavior of monometallic Au and Pd and bimetallic AuPd, it is possible to observe the interaction of the two metals when alloyed. Moreover, we demonstrate that carbon surface has a strong effect on the electrochemical stability of AuPd nanoparticles. By tuning the Au-Pd nanoparticles’ morphology and modulating the surface chemistry of the carbon support, it is possible to obtain materials characterized by novel electrochemical properties. This aspect makes them good candidates to be conveniently applied in different fields." @default.
- W2922876987 created "2019-04-01" @default.
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- W2922876987 date "2019-03-19" @default.
- W2922876987 modified "2023-10-16" @default.
- W2922876987 title "Cyclic Voltammetry Characterization of Au, Pd, and AuPd Nanoparticles Supported on Different Carbon Nanofibers" @default.
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- W2922876987 doi "https://doi.org/10.3390/surfaces2010016" @default.
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