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- W2923081997 abstract "Abstract Ionic liquid functionalized MCM-41 has been synthesized using post-grafting technique. The catalyst denoted as MCM-41-Imi-All/Br was used for the solvent free cycloaddition of several epoxides with carbon dioxide. The low angle powder XRD analysis indicated the presence of several peaks correlating to the (100), (110) and (200) planes typical for MCM-41. The TEM images showed the honeycomb structure of the MCM-41 whereas the average pore width indicates the presence of mesopores predominantly. In addition, the presence of free Br− anions and quaternary nitrogen (N+) species were proven via XPS analysis indicating the successful functionalization of the ionic liquid onto the MCM-41 support. The catalyst exhibited good conversion depending on the functional groups on the epoxides and showed very high selectivity (>95%) for the respective cyclic carbonates." @default.
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- W2923081997 date "2019-06-01" @default.
- W2923081997 modified "2023-10-02" @default.
- W2923081997 title "Highly selective synthesis of cyclic carbonates via solvent free cycloaddition of CO2 and epoxides using ionic liquid grafted on rice husk derived MCM-41" @default.
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- W2923081997 doi "https://doi.org/10.1016/j.inoche.2019.03.012" @default.
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