Matches in SemOpenAlex for { <https://semopenalex.org/work/W2923534734> ?p ?o ?g. }
- W2923534734 endingPage "9869" @default.
- W2923534734 startingPage "9860" @default.
- W2923534734 abstract "α-Azide-ω-alkynyl ester monomers were designed and synthesized in order to obtain hydrolytically degradable polymers. The monomers were prepared from d-galactose, as a renewable resource. Environmentally benign azido-alkyne cycloaddition polymerizations were conducted to afford poly(ester-triazole)s, with complete atom economy. Although polymer formation prevailed under optimized polymerization conditions, variable proportions of cyclic oligomer byproducts were detected. The Cu-catalyzed click polymerization led regioselectively to 1,4-disubstituted triazole linkages, while the thermal, metal-free polymerization produced a random distribution of 1,4- and 1,5-disubstituted triazoles in the polymer backbone. The poly(ester-triazole)s exhibited high molecular weights (Mw in the range 35-85 kDa). They were soluble in organic solvents but highly insoluble in water, thus removal of the Cu(i) catalyst was simplified. The polymers were stable up to 300 °C, and had Tg values in the range 90-100 °C. The materials were hydrolysed under either basic or strong acid conditions, and the degradation products have been characterized." @default.
- W2923534734 created "2019-04-01" @default.
- W2923534734 creator A5032239991 @default.
- W2923534734 creator A5033920484 @default.
- W2923534734 creator A5034786190 @default.
- W2923534734 creator A5079525012 @default.
- W2923534734 creator A5081640431 @default.
- W2923534734 date "2019-01-01" @default.
- W2923534734 modified "2023-10-17" @default.
- W2923534734 title "Synthesis, characterization and chemical degradation of poly(ester-triazole)s derived from <scp>d</scp>-galactose" @default.
- W2923534734 cites W1560627690 @default.
- W2923534734 cites W1968652549 @default.
- W2923534734 cites W1976147365 @default.
- W2923534734 cites W1991771849 @default.
- W2923534734 cites W2017528821 @default.
- W2923534734 cites W2020934764 @default.
- W2923534734 cites W2033945317 @default.
- W2923534734 cites W2034138645 @default.
- W2923534734 cites W2039981960 @default.
- W2923534734 cites W2045043694 @default.
- W2923534734 cites W2046864570 @default.
- W2923534734 cites W2048795280 @default.
- W2923534734 cites W2052048874 @default.
- W2923534734 cites W2052731133 @default.
- W2923534734 cites W2067043061 @default.
- W2923534734 cites W2074741656 @default.
- W2923534734 cites W2098743963 @default.
- W2923534734 cites W2145662716 @default.
- W2923534734 cites W2329896225 @default.
- W2923534734 cites W2336243678 @default.
- W2923534734 cites W2403605818 @default.
- W2923534734 cites W2425970087 @default.
- W2923534734 cites W2462206851 @default.
- W2923534734 cites W2556103485 @default.
- W2923534734 cites W2569799799 @default.
- W2923534734 cites W2577017727 @default.
- W2923534734 cites W2765450078 @default.
- W2923534734 cites W2802435334 @default.
- W2923534734 cites W2824821499 @default.
- W2923534734 cites W4230248169 @default.
- W2923534734 cites W4256503849 @default.
- W2923534734 doi "https://doi.org/10.1039/c9ra00398c" @default.
- W2923534734 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/35520726" @default.
- W2923534734 hasPublicationYear "2019" @default.
- W2923534734 type Work @default.
- W2923534734 sameAs 2923534734 @default.
- W2923534734 citedByCount "10" @default.
- W2923534734 countsByYear W29235347342020 @default.
- W2923534734 countsByYear W29235347342021 @default.
- W2923534734 countsByYear W29235347342022 @default.
- W2923534734 countsByYear W29235347342023 @default.
- W2923534734 crossrefType "journal-article" @default.
- W2923534734 hasAuthorship W2923534734A5032239991 @default.
- W2923534734 hasAuthorship W2923534734A5033920484 @default.
- W2923534734 hasAuthorship W2923534734A5034786190 @default.
- W2923534734 hasAuthorship W2923534734A5079525012 @default.
- W2923534734 hasAuthorship W2923534734A5081640431 @default.
- W2923534734 hasBestOaLocation W29235347341 @default.
- W2923534734 hasConcept C161790260 @default.
- W2923534734 hasConcept C166940927 @default.
- W2923534734 hasConcept C178790620 @default.
- W2923534734 hasConcept C185592680 @default.
- W2923534734 hasConcept C188027245 @default.
- W2923534734 hasConcept C2777907353 @default.
- W2923534734 hasConcept C2779664164 @default.
- W2923534734 hasConcept C2780642029 @default.
- W2923534734 hasConcept C2780997848 @default.
- W2923534734 hasConcept C44228677 @default.
- W2923534734 hasConcept C521977710 @default.
- W2923534734 hasConcept C69610077 @default.
- W2923534734 hasConcept C94412978 @default.
- W2923534734 hasConceptScore W2923534734C161790260 @default.
- W2923534734 hasConceptScore W2923534734C166940927 @default.
- W2923534734 hasConceptScore W2923534734C178790620 @default.
- W2923534734 hasConceptScore W2923534734C185592680 @default.
- W2923534734 hasConceptScore W2923534734C188027245 @default.
- W2923534734 hasConceptScore W2923534734C2777907353 @default.
- W2923534734 hasConceptScore W2923534734C2779664164 @default.
- W2923534734 hasConceptScore W2923534734C2780642029 @default.
- W2923534734 hasConceptScore W2923534734C2780997848 @default.
- W2923534734 hasConceptScore W2923534734C44228677 @default.
- W2923534734 hasConceptScore W2923534734C521977710 @default.
- W2923534734 hasConceptScore W2923534734C69610077 @default.
- W2923534734 hasConceptScore W2923534734C94412978 @default.
- W2923534734 hasFunder F4320321594 @default.
- W2923534734 hasFunder F4320335237 @default.
- W2923534734 hasFunder F4320337954 @default.
- W2923534734 hasIssue "17" @default.
- W2923534734 hasLocation W29235347341 @default.
- W2923534734 hasLocation W29235347342 @default.
- W2923534734 hasLocation W29235347343 @default.
- W2923534734 hasLocation W29235347344 @default.
- W2923534734 hasOpenAccess W2923534734 @default.
- W2923534734 hasPrimaryLocation W29235347341 @default.
- W2923534734 hasRelatedWork W1965082049 @default.
- W2923534734 hasRelatedWork W1991446381 @default.
- W2923534734 hasRelatedWork W2022893325 @default.
- W2923534734 hasRelatedWork W2087766414 @default.