FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2923763896> ?p ?o ?g. }

• W2923763896 endingPage "2693" @default.
• W2923763896 startingPage "2687" @default.
• W2923763896 abstract "With the aim of achieving reversible oxidation and color tuning, the effect of the central aromatic on the spectroscopic, electrochemical, and spectrochemical properties of a series of electrochromic azomethine triads was investigated. The absorption of the alkylated thiophene derivatives was blue-shifted relative to their unalkylated counterparts when the central aromatic was either a bi- or terthiophene. It was further found that the alkylated thiophene derivatives had larger Stokes shifts than their unsubstituted counterparts. Theoretical calculations demonstrated that the torsion angles of these alkylated cores with respect to the flanking azomethines were responsible for the spectroscopic effects. While the electrochemical oxidation potential of the triads varied by only 100 mV, the reversibility of their anodic process was contingent on the central aromatic. The absorption of the electrochemically produced state red-shifted between 165 and 280 nm from its corresponding neutral state, leading to perceived color changes between orange and blue. Reversible color changes were chemically mediated with ferric chloride/hydrazine. The absorption of the chemically oxidized state shifted between 155 and 220 nm from the corresponding neutral state, contingent on the central aromatic. The palette of perceived colors that was possible with oxidation included orange, yellow, blue, and gray." @default.
• W2923763896 created "2019-04-01" @default.
• W2923763896 creator A5022228285 @default.
• W2923763896 creator A5028427743 @default.
• W2923763896 creator A5071822622 @default.
• W2923763896 creator A5085531892 @default.
• W2923763896 date "2019-03-20" @default.
• W2923763896 modified "2023-10-17" @default.
• W2923763896 title "Understanding Color Tuning and Reversible Oxidation of Conjugated Azomethines" @default.
• W2923763896 cites W1088598591 @default.
• W2923763896 cites W1927793650 @default.
• W2923763896 cites W1963806615 @default.
• W2923763896 cites W1964162368 @default.
• W2923763896 cites W1978002275 @default.
• W2923763896 cites W1982721060 @default.
• W2923763896 cites W1998492175 @default.
• W2923763896 cites W2046412723 @default.
• W2923763896 cites W2050740024 @default.
• W2923763896 cites W2058363175 @default.
• W2923763896 cites W2061336776 @default.
• W2923763896 cites W2063711078 @default.
• W2923763896 cites W2120436453 @default.
• W2923763896 cites W2138609916 @default.
• W2923763896 cites W2143981217 @default.
• W2923763896 cites W2159100472 @default.
• W2923763896 cites W2219465728 @default.
• W2923763896 cites W2280090585 @default.
• W2923763896 cites W2301424178 @default.
• W2923763896 cites W2319211965 @default.
• W2923763896 cites W2328363236 @default.
• W2923763896 cites W2347005533 @default.
• W2923763896 cites W2513553777 @default.
• W2923763896 cites W2517476101 @default.
• W2923763896 cites W2546961444 @default.
• W2923763896 cites W2561420799 @default.
• W2923763896 cites W2562724213 @default.
• W2923763896 cites W2566193558 @default.
• W2923763896 cites W2594300186 @default.
• W2923763896 cites W2594440724 @default.
• W2923763896 cites W2595305221 @default.
• W2923763896 cites W2595496559 @default.
• W2923763896 cites W2603654426 @default.
• W2923763896 cites W2611876284 @default.
• W2923763896 cites W2616112651 @default.
• W2923763896 cites W2625636279 @default.
• W2923763896 cites W2735253332 @default.
• W2923763896 cites W2795449088 @default.
• W2923763896 doi "https://doi.org/10.1021/acs.jpca.8b10593" @default.
• W2923763896 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30892894" @default.
• W2923763896 hasPublicationYear "2019" @default.
• W2923763896 type Work @default.
• W2923763896 sameAs 2923763896 @default.
• W2923763896 citedByCount "5" @default.
• W2923763896 countsByYear W29237638962019 @default.
• W2923763896 countsByYear W29237638962020 @default.
• W2923763896 countsByYear W29237638962021 @default.
• W2923763896 crossrefType "journal-article" @default.
• W2923763896 hasAuthorship W2923763896A5022228285 @default.
• W2923763896 hasAuthorship W2923763896A5028427743 @default.
• W2923763896 hasAuthorship W2923763896A5071822622 @default.
• W2923763896 hasAuthorship W2923763896A5085531892 @default.
• W2923763896 hasConcept C101643646 @default.
• W2923763896 hasConcept C109693293 @default.
• W2923763896 hasConcept C112613896 @default.
• W2923763896 hasConcept C147789679 @default.
• W2923763896 hasConcept C159985019 @default.
• W2923763896 hasConcept C161790260 @default.
• W2923763896 hasConcept C164361826 @default.
• W2923763896 hasConcept C17525397 @default.
• W2923763896 hasConcept C178790620 @default.
• W2923763896 hasConcept C185592680 @default.
• W2923763896 hasConcept C192562407 @default.
• W2923763896 hasConcept C2778591166 @default.
• W2923763896 hasConcept C2779604560 @default.
• W2923763896 hasConcept C2779953032 @default.
• W2923763896 hasConcept C521977710 @default.
• W2923763896 hasConcept C52859227 @default.
• W2923763896 hasConcept C73581560 @default.
• W2923763896 hasConcept C75473681 @default.
• W2923763896 hasConceptScore W2923763896C101643646 @default.
• W2923763896 hasConceptScore W2923763896C109693293 @default.
• W2923763896 hasConceptScore W2923763896C112613896 @default.
• W2923763896 hasConceptScore W2923763896C147789679 @default.
• W2923763896 hasConceptScore W2923763896C159985019 @default.
• W2923763896 hasConceptScore W2923763896C161790260 @default.
• W2923763896 hasConceptScore W2923763896C164361826 @default.
• W2923763896 hasConceptScore W2923763896C17525397 @default.
• W2923763896 hasConceptScore W2923763896C178790620 @default.
• W2923763896 hasConceptScore W2923763896C185592680 @default.
• W2923763896 hasConceptScore W2923763896C192562407 @default.
• W2923763896 hasConceptScore W2923763896C2778591166 @default.
• W2923763896 hasConceptScore W2923763896C2779604560 @default.
• W2923763896 hasConceptScore W2923763896C2779953032 @default.
• W2923763896 hasConceptScore W2923763896C521977710 @default.
• W2923763896 hasConceptScore W2923763896C52859227 @default.
• W2923763896 hasConceptScore W2923763896C73581560 @default.
• W2923763896 hasConceptScore W2923763896C75473681 @default.
• W2923763896 hasFunder F4320319952 @default.

• next