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• W2923853093 startingPage "3727" @default.
• W2923853093 abstract "Thiopeptins are a complex of thiopeptide antibiotics similar in structure to thiostrepton and harboring a thioamide, a rare moiety among natural products. Here, we illustrate through a series of in vivo experiments that the thioamide moiety of thiopeptins is generated posttranslationally by a TfuA-YcaO pair, encoded in the thiopeptin biosynthetic gene cluster, before the maturation of the thiopeptide bicyclic scaffold, enhancing the understanding of the biosynthetic logic of thioamide-containing thiopeptides." @default.
• W2923853093 created "2019-04-01" @default.
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• W2923853093 date "2019-01-01" @default.
• W2923853093 modified "2023-10-18" @default.
• W2923853093 title "Insights into the thioamidation of thiopeptins to enhance the understanding of the biosynthetic logic of thioamide-containing thiopeptides" @default.
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• W2923853093 doi "https://doi.org/10.1039/c9ob00402e" @default.
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• W2923853093 hasPublicationYear "2019" @default.
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