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- W2925053775 abstract "The facile synthesis of functionalized organoboron/silicon compounds by copper-catalyzed coupling of alkylsilyl peroxides and diboron/silylborane reagents is reported. The reactions proceed smoothly under mild, neutral conditions in short reaction times to generate organoboron/silicon compounds bearing a ketone moiety, which are useful synthetic intermediates that are otherwise difficult to access. The results of mechanistic investigations suggest the radical-mediated formation of carbon–boron and carbon–silicon bonds via β-scission of alkoxy radicals." @default.
- W2925053775 created "2019-04-01" @default.
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- W2925053775 date "2019-03-26" @default.
- W2925053775 modified "2023-09-28" @default.
- W2925053775 title "Synthesis of Functionalized Organoboron/Silicon Compounds by Copper-Catalyzed Coupling of Alkylsilyl Peroxides and Diboron/Silylborane Reagents" @default.
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- W2925053775 doi "https://doi.org/10.1021/acs.orglett.9b00874" @default.
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