FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2925840629> ?p ?o ?g. }

• W2925840629 endingPage "1297" @default.
• W2925840629 startingPage "1287" @default.
• W2925840629 abstract "This report details the synthesis and characterization of six new Mn(II) complexes coordinated to systematically varied 2,2',2''-nitrilotris(N-arylacetamidate) ligands (LR; R = NO2, Cl, Br, H, Me, and OMe). The complexes are synthesized as the di-tetramethylammonium salts [Me4N]2[MnLR(OAc)]. The nitro variant MnNO2 afforded crystals suitable for X-ray diffraction and its molecular structure is reported. We previously reported the crystal structures of FeNO2 and ZnNO2 and additionally report herein the synthesis and characterization of CoNO2. Using these four molecules, we conduct a brief comparison of the bond metrics to demonstrate that the primary difference governing structural changes is likely due to ionic crystal radii changes rather than electronic properties. The electrochemical properties of the MnR complexes were additionally explored with cyclic voltammetry, which revealed that the series is modulated by the various electronic substituents on the aryl groups of the ligands. The electrochemical studies also revealed, consistent with our previous report, that the acetate ligand on the MnR complexes is labile. Finally, a Hammett plot was constructed using the potentials obtained from cyclic voltammetry, which is compared with a few other similar transition metal complexes." @default.
• W2925840629 created "2019-04-11" @default.
• W2925840629 creator A5007977669 @default.
• W2925840629 creator A5043751476 @default.
• W2925840629 creator A5054833028 @default.
• W2925840629 creator A5058509232 @default.
• W2925840629 creator A5087218721 @default.
• W2925840629 date "2019-04-18" @default.
• W2925840629 modified "2023-09-25" @default.
• W2925840629 title "Electronically varied manganese tris-arylacetamide tripodal complexes" @default.
• W2925840629 cites W1019121302 @default.
• W2925840629 cites W1972770388 @default.
• W2925840629 cites W1976422010 @default.
• W2925840629 cites W2010494742 @default.
• W2925840629 cites W2011474916 @default.
• W2925840629 cites W2038123603 @default.
• W2925840629 cites W2044072818 @default.
• W2925840629 cites W2086135051 @default.
• W2925840629 cites W2120802675 @default.
• W2925840629 cites W2160790360 @default.
• W2925840629 cites W2341795792 @default.
• W2925840629 cites W2754677171 @default.
• W2925840629 cites W2786668874 @default.
• W2925840629 cites W2786699057 @default.
• W2925840629 cites W2807676901 @default.
• W2925840629 doi "https://doi.org/10.1080/00958972.2019.1601714" @default.
• W2925840629 hasPublicationYear "2019" @default.
• W2925840629 type Work @default.
• W2925840629 sameAs 2925840629 @default.
• W2925840629 citedByCount "2" @default.
• W2925840629 countsByYear W29258406292019 @default.
• W2925840629 countsByYear W29258406292021 @default.
• W2925840629 crossrefType "journal-article" @default.
• W2925840629 hasAuthorship W2925840629A5007977669 @default.
• W2925840629 hasAuthorship W2925840629A5043751476 @default.
• W2925840629 hasAuthorship W2925840629A5054833028 @default.
• W2925840629 hasAuthorship W2925840629A5058509232 @default.
• W2925840629 hasAuthorship W2925840629A5087218721 @default.
• W2925840629 hasBestOaLocation W29258406291 @default.
• W2925840629 hasConcept C106773901 @default.
• W2925840629 hasConcept C115624301 @default.
• W2925840629 hasConcept C116569031 @default.
• W2925840629 hasConcept C145148216 @default.
• W2925840629 hasConcept C147789679 @default.
• W2925840629 hasConcept C161790260 @default.
• W2925840629 hasConcept C170493617 @default.
• W2925840629 hasConcept C17525397 @default.
• W2925840629 hasConcept C178790620 @default.
• W2925840629 hasConcept C179104552 @default.
• W2925840629 hasConcept C185592680 @default.
• W2925840629 hasConcept C2182769 @default.
• W2925840629 hasConcept C2777869211 @default.
• W2925840629 hasConcept C2779868791 @default.
• W2925840629 hasConcept C2780263894 @default.
• W2925840629 hasConcept C2781076698 @default.
• W2925840629 hasConcept C2781463628 @default.
• W2925840629 hasConcept C32909587 @default.
• W2925840629 hasConcept C52859227 @default.
• W2925840629 hasConcept C528890316 @default.
• W2925840629 hasConcept C55493867 @default.
• W2925840629 hasConcept C8010536 @default.
• W2925840629 hasConceptScore W2925840629C106773901 @default.
• W2925840629 hasConceptScore W2925840629C115624301 @default.
• W2925840629 hasConceptScore W2925840629C116569031 @default.
• W2925840629 hasConceptScore W2925840629C145148216 @default.
• W2925840629 hasConceptScore W2925840629C147789679 @default.
• W2925840629 hasConceptScore W2925840629C161790260 @default.
• W2925840629 hasConceptScore W2925840629C170493617 @default.
• W2925840629 hasConceptScore W2925840629C17525397 @default.
• W2925840629 hasConceptScore W2925840629C178790620 @default.
• W2925840629 hasConceptScore W2925840629C179104552 @default.
• W2925840629 hasConceptScore W2925840629C185592680 @default.
• W2925840629 hasConceptScore W2925840629C2182769 @default.
• W2925840629 hasConceptScore W2925840629C2777869211 @default.
• W2925840629 hasConceptScore W2925840629C2779868791 @default.
• W2925840629 hasConceptScore W2925840629C2780263894 @default.
• W2925840629 hasConceptScore W2925840629C2781076698 @default.
• W2925840629 hasConceptScore W2925840629C2781463628 @default.
• W2925840629 hasConceptScore W2925840629C32909587 @default.
• W2925840629 hasConceptScore W2925840629C52859227 @default.
• W2925840629 hasConceptScore W2925840629C528890316 @default.
• W2925840629 hasConceptScore W2925840629C55493867 @default.
• W2925840629 hasConceptScore W2925840629C8010536 @default.
• W2925840629 hasIssue "8" @default.
• W2925840629 hasLocation W29258406291 @default.
• W2925840629 hasOpenAccess W2925840629 @default.
• W2925840629 hasPrimaryLocation W29258406291 @default.
• W2925840629 hasRelatedWork W2012345717 @default.
• W2925840629 hasRelatedWork W2013359222 @default.
• W2925840629 hasRelatedWork W2019268601 @default.
• W2925840629 hasRelatedWork W2029325500 @default.
• W2925840629 hasRelatedWork W2075817299 @default.
• W2925840629 hasRelatedWork W2098877051 @default.
• W2925840629 hasRelatedWork W2473277379 @default.
• W2925840629 hasRelatedWork W2519620979 @default.
• W2925840629 hasRelatedWork W2942835415 @default.
• W2925840629 hasRelatedWork W3210149007 @default.
• W2925840629 hasVolume "72" @default.

• next