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- W2925974773 abstract "Hydroquinine 2,5‐diphenyl‐4,6‐pyrimidinediyl diether [(DHQ) 2 Pyr] catalyzed the regio‐, diastereo‐, and enantioselective addition of 4‐substituted pyrazolones to isatin‐derived nitroalkenes, providing a variety of chiral alkenylpyrazolone adducts containing a tetrasubstituted stereocenter bearing an oxindole moiety with excellent yields, regioselectivity, and diastereoselectivity, as well as a moderate enantioselectivity (up to 98 % yield, > 20:1 E/Z ratio dr and 78 % ee ). The reaction harnesses a nitroalkene as an alkenylating agent through a Nucleophilic Vinylic Substitution (S N V) reaction." @default.
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- W2925974773 date "2019-04-18" @default.
- W2925974773 modified "2023-10-16" @default.
- W2925974773 title "Regio-, Diastereo-, and Enantioselective Organocatalytic Addition of 4-Substituted Pyrazolones to Isatin-Derived Nitroalkenes" @default.
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- W2925974773 doi "https://doi.org/10.1002/ejoc.201900328" @default.
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