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• W2926775103 abstract "Abstract A C2-symmetrical N,O-Schiff base ligand containing two hydrazone units has been synthesized and structurally characterized. The solid state structure as determined by single-crystal X-ray diffraction analysis reveals the presence of both intramolecular and intermolecular hydrogen bonds which lead to the formation of a C1-symmetrical conformation as well as a novel one-dimensional (1-D) helical hydrogen-bonded network. The reactions of this bis-hydrazone ligand with zinc(II) and europium (III) salts under appropriate conditions resulted in dinuclear mono-ligand zinc and tri-ligand europium complexes, respectively. The complexes were characterized by NMR spectroscopies, mass spectrometry and elemental analysis. The zinc complex has been further structurally determined by X-ray crystallography. In its solid state structure, the ligand is doubly deprotonated incorporating two zinc(II) cores that are bridged with both phenol-O group and acetate counterions. The solution electronic absorption and emission properties were characterized for both the ligand and zinc complex." @default.
• W2926775103 created "2019-04-11" @default.
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• W2926775103 date "2019-07-01" @default.
• W2926775103 modified "2023-09-26" @default.
• W2926775103 title "Synthesis and structural characterization of dinuclear Zinc(II) and Europium(III) complexes based on a bis-hydrazone ligand" @default.
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• W2926775103 doi "https://doi.org/10.1016/j.molstruc.2019.02.044" @default.
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