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- W2927132854 abstract "Marine tricyclic alkaloids lepadiformine and fasicularin, with a unique perhydropyrrolo[2,1- j]quinoline or perhydropyrido[2,1- j]quinoline framework, were synthesized starting from the B ring of the tricyclic system. This approach includes a highly stereocontrolled diallylation of a cyclic enaminoester and subsequent ring-closing metathesis to construct the A/B ring system, which was transformed into key lactams 32 and 33, and amino alcohol 37. Thus, we achieved formal syntheses of (-)-lepadiformines A, C, and (-)-fasicularin in a divergent manner." @default.
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- W2927132854 date "2019-04-03" @default.
- W2927132854 modified "2023-09-27" @default.
- W2927132854 title "Formal Syntheses of (−)-Lepadiformines A, C, and (−)-Fasicularin" @default.
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- W2927132854 doi "https://doi.org/10.1021/acs.joc.9b00071" @default.
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