FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2927275009> ?p ?o ?g. }

• W2927275009 endingPage "259" @default.
• W2927275009 startingPage "252" @default.
• W2927275009 abstract "Here we show a new insight into the methanol alkylation-efficiency in toluene alkylation. Concretely, nanosheet (SH-), nano-particle (N-), alkali treated (AT-), conventional (C-) HZSM-5 zeolites with similar acidic properties, silica-modified C-HZSM-5 and HSAPO-34 were respectively tested in this catalytic reaction, at an enough high linear velocity of fluid in reactor with eliminating the influence of external diffusion. Combining with the characterizations such as XRD, BET, NH3-TPD, Py-IR, SEM, EDX, probe reactions etc., the effect of ZSM-5 microporous diffusibility on methanol reacting-pathways was studied from the two aspects of (i) the diffusion-constraint at pore-openings and (ii) the effective length of diffusion-reaction path in intracrystal micropore. It was found that the excellent diffusibility (SH-, N- or AT-HZSM-5) can effectively improve the methanol alkylation with aromatics to form desired products. Significantly, up to 96.7% of alkylation-efficiency and 16.4% of toluene conversion were obtained over the ∼10 nm thickness nanosheet HZSM-5 (normal pore-opening diffusion-constraint and shortest diffusion-reaction path) at the 6.0 molar ratio of toluene/methanol. On the contrary, the enhanced pore-opening diffusion-constraint (4Si-C-HZSM-5) or the overlong diffusion-reaction path (C-HZSM-5) resulted in the much lower alkylation-efficiency (38.2% and 67.4% respectively), owing to the enhanced methanol-to-olefins side-reaction with dual-cycle process which converted much more methanol into light aliphatic-hydrocarbons but not the alkyl of aromatics. Our work may provide a theoretical guidance for improving the shape-selective alkylation-efficiency for this reaction process." @default.
• W2927275009 created "2019-04-11" @default.
• W2927275009 creator A5022629505 @default.
• W2927275009 creator A5032057273 @default.
• W2927275009 creator A5039060717 @default.
• W2927275009 creator A5069135250 @default.
• W2927275009 creator A5076839286 @default.
• W2927275009 creator A5079364676 @default.
• W2927275009 date "2019-07-01" @default.
• W2927275009 modified "2023-10-17" @default.
• W2927275009 title "New insight into the alkylation-efficiency of methanol with toluene over ZSM-5: Microporous diffusibility significantly affects reacting-pathways" @default.
• W2927275009 cites W1892848351 @default.
• W2927275009 cites W1967901885 @default.
• W2927275009 cites W1968668678 @default.
• W2927275009 cites W1974221251 @default.
• W2927275009 cites W1980246087 @default.
• W2927275009 cites W1986559518 @default.
• W2927275009 cites W1986703948 @default.
• W2927275009 cites W1992367153 @default.
• W2927275009 cites W1992898958 @default.
• W2927275009 cites W2002847402 @default.
• W2927275009 cites W2005843732 @default.
• W2927275009 cites W2014756801 @default.
• W2927275009 cites W2017173483 @default.
• W2927275009 cites W2020051363 @default.
• W2927275009 cites W2041073159 @default.
• W2927275009 cites W2046816335 @default.
• W2927275009 cites W2053428471 @default.
• W2927275009 cites W2055309047 @default.
• W2927275009 cites W2057425059 @default.
• W2927275009 cites W2059664956 @default.
• W2927275009 cites W2060328010 @default.
• W2927275009 cites W2076945120 @default.
• W2927275009 cites W2078693135 @default.
• W2927275009 cites W2079592981 @default.
• W2927275009 cites W2082952862 @default.
• W2927275009 cites W2115174549 @default.
• W2927275009 cites W2120054388 @default.
• W2927275009 cites W2169571222 @default.
• W2927275009 cites W2175780999 @default.
• W2927275009 cites W2287415013 @default.
• W2927275009 cites W2313150585 @default.
• W2927275009 cites W2315694658 @default.
• W2927275009 cites W2315767686 @default.
• W2927275009 cites W2370859362 @default.
• W2927275009 cites W2468900259 @default.
• W2927275009 cites W2558920454 @default.
• W2927275009 cites W2619261433 @default.
• W2927275009 cites W2760877105 @default.
• W2927275009 cites W2765272465 @default.
• W2927275009 cites W2766644885 @default.
• W2927275009 cites W2767659672 @default.
• W2927275009 cites W2793875168 @default.
• W2927275009 cites W3145772412 @default.
• W2927275009 cites W33237271 @default.
• W2927275009 doi "https://doi.org/10.1016/j.micromeso.2019.03.040" @default.
• W2927275009 hasPublicationYear "2019" @default.
• W2927275009 type Work @default.
• W2927275009 sameAs 2927275009 @default.
• W2927275009 citedByCount "24" @default.
• W2927275009 countsByYear W29272750092019 @default.
• W2927275009 countsByYear W29272750092020 @default.
• W2927275009 countsByYear W29272750092021 @default.
• W2927275009 countsByYear W29272750092022 @default.
• W2927275009 countsByYear W29272750092023 @default.
• W2927275009 crossrefType "journal-article" @default.
• W2927275009 hasAuthorship W2927275009A5022629505 @default.
• W2927275009 hasAuthorship W2927275009A5032057273 @default.
• W2927275009 hasAuthorship W2927275009A5039060717 @default.
• W2927275009 hasAuthorship W2927275009A5069135250 @default.
• W2927275009 hasAuthorship W2927275009A5076839286 @default.
• W2927275009 hasAuthorship W2927275009A5079364676 @default.
• W2927275009 hasConcept C121332964 @default.
• W2927275009 hasConcept C127413603 @default.
• W2927275009 hasConcept C161790260 @default.
• W2927275009 hasConcept C164361826 @default.
• W2927275009 hasConcept C178790620 @default.
• W2927275009 hasConcept C185592680 @default.
• W2927275009 hasConcept C2778142098 @default.
• W2927275009 hasConcept C2779607525 @default.
• W2927275009 hasConcept C42360764 @default.
• W2927275009 hasConcept C69357855 @default.
• W2927275009 hasConcept C86381522 @default.
• W2927275009 hasConcept C97355855 @default.
• W2927275009 hasConceptScore W2927275009C121332964 @default.
• W2927275009 hasConceptScore W2927275009C127413603 @default.
• W2927275009 hasConceptScore W2927275009C161790260 @default.
• W2927275009 hasConceptScore W2927275009C164361826 @default.
• W2927275009 hasConceptScore W2927275009C178790620 @default.
• W2927275009 hasConceptScore W2927275009C185592680 @default.
• W2927275009 hasConceptScore W2927275009C2778142098 @default.
• W2927275009 hasConceptScore W2927275009C2779607525 @default.
• W2927275009 hasConceptScore W2927275009C42360764 @default.
• W2927275009 hasConceptScore W2927275009C69357855 @default.
• W2927275009 hasConceptScore W2927275009C86381522 @default.
• W2927275009 hasConceptScore W2927275009C97355855 @default.
• W2927275009 hasFunder F4320321001 @default.
• W2927275009 hasFunder F4320324780 @default.

• next