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• W2927783463 endingPage "5220" @default.
• W2927783463 startingPage "5211" @default.
• W2927783463 abstract "Syntheses of a novel pseudotetrahedral four-coordinate mononuclear Co(II) complex that has two halved phthalocyanine moieties as the ligands, [Co(half-Pc)2] (1), and its magnetic properties as a single molecule magnet (SMM) are reported. A one pot reaction of phthalonitrile and lithium methoxide followed by the coordination to a Co(II) ion gave 1 as an orange solid in a moderate yield. X-ray crystallography on 1 reveals tetragonally distorted coordination geometry around the Co(II) ion. The M–HT–1 plots suggest that 1 has large axial magnetic anisotropy. The ac magnetic susceptibility data of the magnetically diluted 1 (dil.1) clearly show that the complex acts as an SMM even in the absence of the external static magnetic field (Hdc). The influence of intermolecular and intramolecular interactions for the magnetic relaxation behaviors has been discussed by comparison of the magnetic data of 1 and dil.1. The Orbach process is suggested as the predominant mechanism of magnetic relaxations in the high-temperature range, and the Arrhenius plots provide the effective relaxation energy barrier and pre-exponential factor of Ueff = 54.0 cm–1 and τ0 = 3.17 × 10–10 s, respectively. The direct estimation of the axial anisotropic parameter of 1 was successfully performed by high-field, multifrequency ESR measurements up to 55 T and 2.5 THz. The evaluated axial zero-field splitting (ZFS) energy of 57.0 cm–1 is comparable to the Ueff energy, confirming that the magnetic relaxations are initiated by the thermal excitation from the ground |MS⟩ = |±3/2⟩ states to the |±1/2⟩ states in the high-temperature range. The results of the ab initio calculations based on the CAS(7,5) SCF wave functions indicate that the ground states of 1 consist mainly of |MS⟩ = |±3/2⟩ states, while the first excited states are the mixture of |MS⟩ = |+1/2⟩ and |−1/2⟩." @default.
• W2927783463 created "2019-04-11" @default.
• W2927783463 creator A5001345070 @default.
• W2927783463 creator A5034057772 @default.
• W2927783463 creator A5034328269 @default.
• W2927783463 creator A5038827924 @default.
• W2927783463 creator A5040598452 @default.
• W2927783463 creator A5084922929 @default.
• W2927783463 date "2019-04-01" @default.
• W2927783463 modified "2023-10-03" @default.
• W2927783463 title "Synthesis of a Neutral Mononuclear Four-Coordinate Co(II) Complex Having Two Halved Phthalocyanine Ligands That Shows Slow Magnetic Relaxations under Zero Static Magnetic Field" @default.
• W2927783463 cites W1720276026 @default.
• W2927783463 cites W1782771317 @default.
• W2927783463 cites W1798281623 @default.
• W2927783463 cites W1832906531 @default.
• W2927783463 cites W1834882820 @default.
• W2927783463 cites W1955518466 @default.
• W2927783463 cites W1962539607 @default.
• W2927783463 cites W1968751790 @default.
• W2927783463 cites W1970881901 @default.
• W2927783463 cites W1973537412 @default.
• W2927783463 cites W1978239898 @default.
• W2927783463 cites W1985350988 @default.
• W2927783463 cites W1992996545 @default.
• W2927783463 cites W1999921319 @default.
• W2927783463 cites W2002513419 @default.
• W2927783463 cites W2003618810 @default.
• W2927783463 cites W2006732735 @default.
• W2927783463 cites W2012202243 @default.
• W2927783463 cites W2012419965 @default.
• W2927783463 cites W2015743491 @default.
• W2927783463 cites W2044150055 @default.
• W2927783463 cites W2045894490 @default.
• W2927783463 cites W2046897274 @default.
• W2927783463 cites W2047000596 @default.
• W2927783463 cites W2059452547 @default.
• W2927783463 cites W2061797679 @default.
• W2927783463 cites W2067718414 @default.
• W2927783463 cites W2087266110 @default.
• W2927783463 cites W2089740902 @default.
• W2927783463 cites W2091901086 @default.
• W2927783463 cites W2098702989 @default.
• W2927783463 cites W2102371356 @default.
• W2927783463 cites W2107826958 @default.
• W2927783463 cites W2129451637 @default.
• W2927783463 cites W2129821016 @default.
• W2927783463 cites W2131350133 @default.
• W2927783463 cites W2145339008 @default.
• W2927783463 cites W2153446935 @default.
• W2927783463 cites W2154229956 @default.
• W2927783463 cites W2165754131 @default.
• W2927783463 cites W2174722686 @default.
• W2927783463 cites W2190133988 @default.
• W2927783463 cites W2211195160 @default.
• W2927783463 cites W2223942443 @default.
• W2927783463 cites W2278356249 @default.
• W2927783463 cites W2286909909 @default.
• W2927783463 cites W2299627883 @default.
• W2927783463 cites W2313741833 @default.
• W2927783463 cites W2316457736 @default.
• W2927783463 cites W2317109302 @default.
• W2927783463 cites W2328678682 @default.
• W2927783463 cites W2330164190 @default.
• W2927783463 cites W2330961444 @default.
• W2927783463 cites W2332018527 @default.
• W2927783463 cites W2332402427 @default.
• W2927783463 cites W2346335541 @default.
• W2927783463 cites W2414402924 @default.
• W2927783463 cites W2439570865 @default.
• W2927783463 cites W2474440651 @default.
• W2927783463 cites W2507176797 @default.
• W2927783463 cites W2519424975 @default.
• W2927783463 cites W2519534238 @default.
• W2927783463 cites W2528136433 @default.
• W2927783463 cites W2549302171 @default.
• W2927783463 cites W2552655864 @default.
• W2927783463 cites W2566335857 @default.
• W2927783463 cites W2592672544 @default.
• W2927783463 cites W2594716782 @default.
• W2927783463 cites W2606629383 @default.
• W2927783463 cites W2616557405 @default.
• W2927783463 cites W2618436321 @default.
• W2927783463 cites W2621844366 @default.
• W2927783463 cites W2625912678 @default.
• W2927783463 cites W2739439285 @default.
• W2927783463 cites W2749576414 @default.
• W2927783463 cites W2752102549 @default.
• W2927783463 cites W2765251211 @default.
• W2927783463 cites W2791736661 @default.
• W2927783463 cites W2796898806 @default.
• W2927783463 cites W2839640801 @default.
• W2927783463 cites W2896968078 @default.
• W2927783463 cites W2901080522 @default.
• W2927783463 cites W2902532606 @default.
• W2927783463 cites W2951865839 @default.
• W2927783463 cites W3037853801 @default.
• W2927783463 cites W4212913169 @default.
• W2927783463 doi "https://doi.org/10.1021/acs.inorgchem.9b00286" @default.

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