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- W2928041390 abstract "Abstract A concise and highly stereoselective synthesis of alkynyloxazolines via a gold‐catalyzed domino cyclization‐alkynylation cascade of N ‐propargylcarboxamides with benziodoxole reagents is reported. This new protocol, which represents an attractive alternative to two step sequences based on Sonagashira couplings, offers a broad substrate scope, excellent functional group tolerance, and perfect stereoselectivity. A comparison of the computed energies of the isomers of the product suggests kinetic control as the cause of the observed selectivity. magnified image" @default.
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- W2928041390 date "2019-04-29" @default.
- W2928041390 modified "2023-10-16" @default.
- W2928041390 title "Gold‐Catalyzed Stereoselective Domino Cyclization/Alkynylation of <i>N</i>‐Propargylcarboxamides with Benziodoxole Reagents for the Synthesis of Alkynyloxazolines" @default.
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- W2928041390 doi "https://doi.org/10.1002/adsc.201900264" @default.
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