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- W2928855904 abstract "Herein, we demonstrated the development of a non-enzymatic glucose sensor based on a metal azolate framework (MAF-4-CoII or Co(mim)2, mim = 2-methylimidazole)-modified glassy carbon electrode (GCE). The as-synthesized MAF-4-CoII exhibited high crystallinity, purity, and chemical and electrochemical stability, which was characterized by various analytical methods. The MAF-4-CoII exhibited good redox activity in the alkaline medium due to the formation of MAF-4-CoII/MAF-4-CoIII redox pair, which concurrently induced the non-enzymatic oxidation of glucose to gluconolactone. The MAF-4-CoII/GCE sensor exhibited wide dynamic ranges in the concentration range from 2 to 50 μM and 100 to 1800 μM with high sensitivity (ca. 990.90 and 30.95 μA/cm2/mM, respectively), low detection limit (ca. 0.60 μM), reproducibility, and selectivity. The practical applicability of this sensor was evaluated using diluted human serum samples, which revealed excellent recoveries of glucose. Thus, MAF-4-CoII can be used as a promising electrocatalyst for non-enzymatic detection of glucose with high stability." @default.
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- W2928855904 date "2019-05-01" @default.
- W2928855904 modified "2023-09-25" @default.
- W2928855904 title "A chemically and electrochemically stable, redox-active and highly sensitive metal azolate framework for non-enzymatic electrochemical detection of glucose" @default.
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- W2928855904 doi "https://doi.org/10.1016/j.jelechem.2019.03.081" @default.
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