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- W2929804931 abstract "Abstract Two isotypical Cd(II) based one‐dimensional coordination polymers (1D CPs) [Cd 2 ( p ‐clba) 4 (bpy) 2 ]⋅(C 2 H 5 OH) ( 1 ) and [Cd 2 ( p ‐brba) 4 (bpy) 2 ]⋅(C 2 H 5 OH), ( 2 ) (H 2 p ‐clba= para ‐chlorobenzoic acid, H 2 p ‐brba= para ‐bromobenzoic acid and bpy=4,4′‐bipyridine) have been synthesized and characterized by X‐ray structure analysis. In the solid‐state strcuture, both the compounds undergo X⋅⋅⋅п (X=Cl or Br) interactions to generate two‐dimensional (2D) supramolecular architectures. Here, due to the larger size and more polarisability of Br atom, Br⋅⋅⋅п interaction is stronger than Cl⋅⋅⋅п, which is accounted for the stronger interchain interactions in 2 as compared to 1 . This is depicted in the observed electrical conductivity of the compounds. The compound 2 with stronger interchain interactions shows better charge transport and hence, increasing conductivity. Moreover, band gap of the CPs has been obtained by DFT computation, which also supports the progression of conductivity." @default.
- W2929804931 created "2019-04-11" @default.
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- W2929804931 date "2019-03-25" @default.
- W2929804931 modified "2023-10-02" @default.
- W2929804931 title "Halogen⋅⋅⋅π Interactions in Supramolecular Architecture of 1D Coordination Polymers and Their Electrical Conductance" @default.
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- W2929804931 doi "https://doi.org/10.1002/slct.201900578" @default.
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