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- W2931036966 endingPage "5175" @default.
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- W2931036966 abstract "Enantioselective syntheses of hexacyclic aspidoalbidine alkaloids (+)-fendleridine (2) and (+)-acetylaspidoalbidine (3) are described. These syntheses feature an asymmetric decarboxylative allylation and photocyclization of a highly substituted enaminone. Also, the synthesis highlights the formation of a C19-hemiaminal ether via a reduction/condensation/intramolecular cyclization cascade with the C21-alcohol. The present synthesis provides convenient access to the aspidoalbidine hexacyclic alkaloid family in an efficient manner." @default.
- W2931036966 created "2019-04-11" @default.
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- W2931036966 date "2019-04-02" @default.
- W2931036966 modified "2023-10-17" @default.
- W2931036966 title "Enantioselective Total Syntheses of (+)-Fendleridine and (+)-Acetylaspidoalbidine" @default.
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- W2931036966 doi "https://doi.org/10.1021/acs.joc.9b00145" @default.
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