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- W2931383933 abstract "A molecular system inducing an accumulative unidirectional rotation motion of glass flakes with about 100 μm in size is introduced. The molecular system is a chiral nematic liquid crystal containing a chiral azobenzene derivative which shows a reversible E- Z photoisomerization accompanying a large helical twisting power change. A film of the molecular system shows different texture change paths upon UV and visible light irradiations inducing E to Z and Z to E photoisomerizations, respectively, of the chiral azobenzene dopant. Namely, a polygonal fingerprint texture inducing the rotation of glass flakes on the film surface was maintained during UV irradiation, while a focal conic texture inducing no rotation of glass flakes emerged during visible light irradiation. As a result, cycles of the alternative irradiation of UV and visible lights afforded many rotations toward a single direction of the glass flakes which can be considered as a continuous conversion of light energy to mechanical work. We may compare the effect of this molecular system converting back and forth structural change between E and Z isomers of the chiral azobenzene to a continuous rotational motion of glass flakes with the crankshaft effect converting a piston-like motion to a rotational motion seen in engines in the real world." @default.
- W2931383933 created "2019-04-11" @default.
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- W2931383933 date "2019-04-01" @default.
- W2931383933 modified "2023-09-29" @default.
- W2931383933 title "Molecular Crankshaft Effect Converting Piston-like Molecular Motion to Continuous Rotation of Macro Objects" @default.
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- W2931383933 doi "https://doi.org/10.1021/acsami.9b03706" @default.
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