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• W2932073265 abstract "Reactions of ortho-fluorinated anilines with stoichiometric Ti(NMe2)4 in mesitylene (typically for 23 h at 120 °C) afforded moderate to high yields of the corresponding N,N-dimethyl-1,2-phenylenediamine derivatives resulting from defluoroamination of a fluorine atom vicinal to the NH2 of the starting aniline. Reactivity increases with additional ring fluorination in general accordance with established regiochemical (activating and deactivating) trends." @default.
• W2932073265 created "2019-04-11" @default.
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• W2932073265 date "2019-08-01" @default.
• W2932073265 modified "2023-09-26" @default.
• W2932073265 title "Regioselective, nucleophilic activation of C F bonds in o-fluoroanilines" @default.
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• W2932073265 doi "https://doi.org/10.1016/j.jfluchem.2019.03.009" @default.
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