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- W2932752624 abstract "We investigated the effect of the morphological structure of a graphene oxide (GO) monolayer on the dewetting dynamics of the upper polymer thin films. The Langmuir-Schaefer (LS) technique was used to prepare a wrinkled GO ( wrGO) structure with a root mean square (rms) roughness of 22.7 Å. The dewetting behavior of poly(methyl methacrylate) (PMMA) thin films on the wrGO monolayers was perfectly prevented, whereas the PMMA thin films on a flat GO monolayer were dewetted at 203 °C. This wrinkle effect of the GO can be also obtained when the GOs monolayers are intercalated to the PMMA/polystyrene (PS) interface. In this multilayer, the flat GO monolayer at the interface between the PS and PMMA layers was spontaneously roughened with rms roughness of 46.9 Å after annealing and also prohibited the dewetting behavior. From the results, we found that to improve the compatibility of polymer blends by adding the two-dimensional nanosheets, it is important to control the morphological structure of the sheets at the interface, along with manipulation of the GO-polymer interactions." @default.
- W2932752624 created "2019-04-11" @default.
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- W2932752624 date "2019-03-31" @default.
- W2932752624 modified "2023-09-24" @default.
- W2932752624 title "Dewetting of Thin Polymer Films on Wrinkled Graphene Oxide Monolayers" @default.
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- W2932752624 doi "https://doi.org/10.1021/acs.langmuir.9b00141" @default.
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