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• W2933341490 abstract "Abstract Enantioselective total syntheses of pseudopteroxazole ( 1 ) and ileabethoxazole ( 2 ) are presented. The two original stereocenters were constructed in excellent enantioselectivity and good diastereoselectivity through Carreira's asymmetric dual catalytic allylation, which shows potential for accessing diastereoisomers at C2 and C3 of 1 and 2 . Cationic cyclizations of 13 and 24 demonstrated an effective pathway for the construction of the opposite configurations at C1 in 1 and 2 . Additionally, an approach for the introduction of methyl at C4 is a feasible solution for structural modifications at C4 in 1 and 2 ." @default.
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• W2933341490 date "2019-04-26" @default.
• W2933341490 modified "2023-09-23" @default.
• W2933341490 title "Enantioselective Total Synthesis of Pseudopteroxazole and Ileabethoxazole" @default.
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• W2933341490 doi "https://doi.org/10.1002/anie.201901651" @default.
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