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• W2933741489 startingPage "13198" @default.
• W2933741489 abstract "Minimal Mn dissolution was achieved with surface Mn4+-rich phase-modified truncated octahedral spinel LiMn2O4 with exposed {111} planes, which was synthesized via a simple hydrothermal reaction, followed by high temperature calcination in an oxygen atmosphere. The calcination atmosphere had a significant influence on the formation of the surface Mn4+-rich phase-modified layer; LiMn2O4 without a surface Mn4+-rich phase was obtained by calcination in an air atmosphere. Benefiting from the unique structure, the as-prepared LiMn2O4 exhibited an excellent rate capability and prolonged cycle stability, delivering a discharge capacity of 101 mAh g−1 and capacity retention rates of about 94% and 88% after 500 and 1000 cycles at 1C, respectively, compared to a discharge capacity of 86 mAh g−1 and a capacity retention rate of about 86% after 500 cycles at 1C for the LiMn2O4 prepared in an air atmosphere. The synergistic effect of the unique truncated octahedral morphology of spinel LiMn2O4 with {111} exposed planes and the modification of the surface Mn-rich phase endowed the composite with excellent electrochemical properties." @default.
• W2933741489 created "2019-04-11" @default.
• W2933741489 creator A5006773009 @default.
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• W2933741489 date "2019-07-01" @default.
• W2933741489 modified "2023-10-13" @default.
• W2933741489 title "Spinel LiMn2O4 cathode materials for lithium storage: The regulation of exposed facets and surface coating" @default.
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• W2933741489 doi "https://doi.org/10.1016/j.ceramint.2019.04.002" @default.
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