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- W2935598894 abstract "Phosphole P(V) derivatives are interesting building blocks for various applications from ligand synthesis to material sciences. We herein describe the preparation and characterisation of new 2,4-disubstituted oxo-, thiooxo-, and selenooxophospholes. The nature of the substituents on the phosphole ring determines the reactivity of these compounds towards homodimerization reactions. Aryl and trimethylsilyl substituted oxophospholes undergo selective <mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML id=M1><mml:mrow><mml:mo stretchy=false>[</mml:mo></mml:mrow></mml:math>4+2] dimerization, whereas, for thiooxo- and selenooxophospholes, light-induced, selective <mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML id=M2><mml:mrow><mml:mo stretchy=false>[</mml:mo></mml:mrow></mml:math>2+2] head-to-head dimerization occurs in the case of aryl substituents. DFT calculations provide some insights on these differences in reactivity." @default.
- W2935598894 created "2019-04-11" @default.
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- W2935598894 date "2019-04-01" @default.
- W2935598894 modified "2023-09-25" @default.
- W2935598894 title "[4+2] versus [2+2] Homodimerization in P(V) Derivatives of 2,4-Disubstituted Phospholes" @default.
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- W2935598894 doi "https://doi.org/10.1155/2019/2596405" @default.
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