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• W2935834357 abstract "The effect of nanoparticle shape on the ionic conductivity and thermal properties of solid polymer electrolytes is reported. Poly(ethylene oxide) (PEO) and LiClO4 electrolytes with an ether oxygen to Li+ molar ratio of 10:1 are filled with TiO2 nanorods and elliptical-shaped fillers in the concentration ranges of 1–2.5 and 1–10 wt %, respectively. The filler concentration that provides the maximum improvement in the ionic conductivity scales inversely with aspect ratio (AR): 10 wt % for spherical nanoparticles (AR = 1), 5 wt % for ellipses (AR ≈ 4.4), and 1–2 wt % for nanorods (AR ≈ 6.6). The same trend is true for Fe2O3 nanofillers, suggesting that the observation is independent of the chemical identity of the metal oxide filler. While the filler concentration required to maximize the conductivity improvement is correlated to the nanofiller shape, the magnitude of the improvement is correlated to the surface-to-volume ratio of the filler. Specifically, the conductivity increases 1 order of magnitude by increasing the surface-to-volume ratio by 5×, illustrating the critical role of the filler surface and suggesting that ion transport is favored at the electrolyte–filler interface over the bulk. Thermal measurements indicate an unexpected relationship between crystallinity and conductivity: the room-temperature conductivity of the electrolyte with 2 wt % TiO2 nanorods is 1 order of magnitude higher than that with 5 wt % elliptical TiO2, even though the nanorod sample is semicrystalline while the elliptical sample is amorphous. The results uncover shape–property relationships that can serve as design rules for solid polymer electrolytes filled with metal oxide nanofillers." @default.
• W2935834357 created "2019-04-25" @default.
• W2935834357 creator A5005300037 @default.
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• W2935834357 date "2019-04-11" @default.
• W2935834357 modified "2023-10-02" @default.
• W2935834357 title "Effect of Nanoparticle Shape on the Electrical and Thermal Properties of Solid Polymer Electrolytes" @default.
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• W2935834357 doi "https://doi.org/10.1021/acs.jpcc.8b08029" @default.
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