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- W2935849394 abstract "A method for the first direct insertion of difluorcarbene, generated from TMSCF3, into diselenides and disulfides is disclosed, producing novel difluoromethyl diselenoacetals and difluoromethyl dithioacetals. The reaction conditions tolerate a range of synthetically useful and biologically relevant functional groups. The process is scalable, with two representative compounds prepared at a gram-scale in good yields, and it utilizes cheap and available reagents." @default.
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- W2935849394 date "2019-08-01" @default.
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- W2935849394 title "One-pot preparation of (RSe)2CF2 and (RS)2CF2 compounds via insertion of TMSCF3-derived difluorocarbene into diselenides and disulfides" @default.
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- W2935849394 doi "https://doi.org/10.1016/j.tet.2019.04.042" @default.
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