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- W2936026972 abstract "Concepts for the thermodynamically challenging synthesis of weak N-H bonds by photoinduced proton coupled electron transfer are explored. Upon irradiation with blue light, ammonia synthesis was achieved from the manganese nitride (tBuSalen)MnN (tBuSalen = (S,S)-(+)-N,N'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine) in the presence of 9,10-dihydroacridine and a ruthenium photocatalyst in iPrOH solution. Although in one case the ruthenium complex bears a remote N-H bond that weakens to 41 kcal mol-1 upon irradiation, control experiments with the N-methylated analog demonstrate the ruthenium complex serves as a photoreductant rather than hydrogen-atom transfer catalyst in aprotic solvents. Luminescence quenching experiments support a ruthenium(ii)/(iii) cycle rather than a ruthenium(i)/(ii) alternative. Identification of the manganese complex following ammonia synthesis was also accomplished." @default.
- W2936026972 created "2019-04-25" @default.
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- W2936026972 date "2019-01-01" @default.
- W2936026972 modified "2023-10-17" @default.
- W2936026972 title "Evaluation of excited state bond weakening for ammonia synthesis from a manganese nitride: stepwise proton coupled electron transfer is preferred over hydrogen atom transfer" @default.
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- W2936026972 doi "https://doi.org/10.1039/c9cc01046g" @default.
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