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• W2936308481 endingPage "5694" @default.
• W2936308481 startingPage "5684" @default.
• W2936308481 abstract "Free amino group-directed C(sp3)–H functionalization of aliphatic amines is a fundamental challenge in synthetic organic chemistry. Also, the NH2-directed C(sp3)–H functionalization of α-amino acids and their derivatives remains barely explored. With palladium as the catalyst and Ag2O as the additive, we developed the first NH2-directed γ-C(sp3)–H arylation of α-amino esters with diaryliodonium triflates for the construction of synthetically useful γ-aryl-α-amino esters, and the result of the KIE study suggested that the catalytic reaction involved an irreversible C–H cleavage as the rate-determining step." @default.
• W2936308481 created "2019-04-25" @default.
• W2936308481 creator A5017993225 @default.
• W2936308481 creator A5024407258 @default.
• W2936308481 creator A5062197457 @default.
• W2936308481 creator A5090546948 @default.
• W2936308481 date "2019-04-08" @default.
• W2936308481 modified "2023-10-14" @default.
• W2936308481 title "Free Amino Group-Directed γ-C(sp³)–H Arylation of α-Amino Esters with Diaryliodonium Triflates by Palladium Catalysis" @default.
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• W2936308481 doi "https://doi.org/10.1021/acs.joc.9b00605" @default.

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