Matches in SemOpenAlex for { <https://semopenalex.org/work/W2936698449> ?p ?o ?g. }
- W2936698449 endingPage "8823" @default.
- W2936698449 startingPage "8819" @default.
- W2936698449 abstract "Abstract In recent years, interest in shape‐persistent organic cage compounds has steadily increased, not least because dynamic covalent bond formation enables such structures to be made in high to excellent yields. One often used type of dynamic bond formation is the generation of an imine bond from an aldehyde and an amine. Although the reversibility of the imine bond formation is advantageous for high yields, it is disadvantageous for the chemical stability of the compounds. Amide bonds are, in contrast to imine bonds much more robust. Shape‐persistent amide cages have so far been made by irreversible amide bond formations in multiple steps, very often accompanied by low yields. Here, we present an approach to shape‐persistent amide cages by exploiting a high‐yielding reversible cage formation in the first step, and a Pinnick oxidation as a key step to access the amide cages in just three steps. These chemically robust amide cages can be further transformed by bromination or nitration to allow post‐functionalization in high yields. The impact of the substituents on the gas sorption behavior was also investigated." @default.
- W2936698449 created "2019-04-25" @default.
- W2936698449 creator A5017497850 @default.
- W2936698449 creator A5034033730 @default.
- W2936698449 creator A5036715884 @default.
- W2936698449 creator A5043398784 @default.
- W2936698449 creator A5058654648 @default.
- W2936698449 creator A5084670164 @default.
- W2936698449 creator A5086516224 @default.
- W2936698449 date "2019-05-17" @default.
- W2936698449 modified "2023-10-18" @default.
- W2936698449 title "Transformation of a [4+6] Salicylbisimine Cage to Chemically Robust Amide Cages" @default.
- W2936698449 cites W1881568159 @default.
- W2936698449 cites W1967153300 @default.
- W2936698449 cites W1967906197 @default.
- W2936698449 cites W1971272447 @default.
- W2936698449 cites W1987845146 @default.
- W2936698449 cites W1989887817 @default.
- W2936698449 cites W1992043705 @default.
- W2936698449 cites W1993395069 @default.
- W2936698449 cites W2009046603 @default.
- W2936698449 cites W2014594932 @default.
- W2936698449 cites W2022410019 @default.
- W2936698449 cites W2027345363 @default.
- W2936698449 cites W2030216757 @default.
- W2936698449 cites W2039971932 @default.
- W2936698449 cites W2041391330 @default.
- W2936698449 cites W2043521588 @default.
- W2936698449 cites W2044131151 @default.
- W2936698449 cites W2044141323 @default.
- W2936698449 cites W2048096852 @default.
- W2936698449 cites W2049604820 @default.
- W2936698449 cites W2064741092 @default.
- W2936698449 cites W2067768339 @default.
- W2936698449 cites W2077125308 @default.
- W2936698449 cites W2087155016 @default.
- W2936698449 cites W2087236866 @default.
- W2936698449 cites W2087797040 @default.
- W2936698449 cites W2092729820 @default.
- W2936698449 cites W2095274012 @default.
- W2936698449 cites W2103714898 @default.
- W2936698449 cites W2105044670 @default.
- W2936698449 cites W2109107738 @default.
- W2936698449 cites W2114575672 @default.
- W2936698449 cites W2117347832 @default.
- W2936698449 cites W2118467593 @default.
- W2936698449 cites W2126771063 @default.
- W2936698449 cites W2127980606 @default.
- W2936698449 cites W2130881995 @default.
- W2936698449 cites W2138495460 @default.
- W2936698449 cites W2140065574 @default.
- W2936698449 cites W2143696504 @default.
- W2936698449 cites W2145538332 @default.
- W2936698449 cites W2146011455 @default.
- W2936698449 cites W2146152455 @default.
- W2936698449 cites W2153597086 @default.
- W2936698449 cites W2157740440 @default.
- W2936698449 cites W2161228776 @default.
- W2936698449 cites W2168308494 @default.
- W2936698449 cites W2168843969 @default.
- W2936698449 cites W2168974120 @default.
- W2936698449 cites W2170995408 @default.
- W2936698449 cites W2171686804 @default.
- W2936698449 cites W2275381896 @default.
- W2936698449 cites W2318204657 @default.
- W2936698449 cites W2422734291 @default.
- W2936698449 cites W2500001324 @default.
- W2936698449 cites W2531963788 @default.
- W2936698449 cites W2551020416 @default.
- W2936698449 cites W2561242334 @default.
- W2936698449 cites W2563395883 @default.
- W2936698449 cites W2596279921 @default.
- W2936698449 cites W2733687454 @default.
- W2936698449 cites W2775771329 @default.
- W2936698449 cites W2778829115 @default.
- W2936698449 cites W2781488361 @default.
- W2936698449 cites W2791324493 @default.
- W2936698449 cites W2892214103 @default.
- W2936698449 cites W2898866616 @default.
- W2936698449 cites W2912419238 @default.
- W2936698449 cites W2936698449 @default.
- W2936698449 cites W4231227339 @default.
- W2936698449 cites W4231560593 @default.
- W2936698449 cites W4232529058 @default.
- W2936698449 cites W4235279171 @default.
- W2936698449 cites W4236070065 @default.
- W2936698449 cites W4236644077 @default.
- W2936698449 cites W4237815761 @default.
- W2936698449 cites W4240945068 @default.
- W2936698449 cites W4242895839 @default.
- W2936698449 cites W4243858333 @default.
- W2936698449 cites W4249001014 @default.
- W2936698449 cites W4250834041 @default.
- W2936698449 cites W4376043627 @default.
- W2936698449 cites W4376596063 @default.
- W2936698449 cites W843007777 @default.
- W2936698449 doi "https://doi.org/10.1002/anie.201903631" @default.
- W2936698449 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/6618138" @default.