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- W2936736639 abstract "Abstract Based on the structural similarities of the recently isolated eremophilane‐type sesquiterpenoids microsphaeropsisin B and C and the iso ‐eremophilane periconianone C, a revised biogenetic hypothesis for C8–C11‐connected iso ‐eremophilanes is presented and corroborated by strong experimental evidence. The first enantioselective total syntheses of microsphaeropsisin B and C were achieved starting from a known intermediate, whose synthesis was elaborated previously in the total synthesis of periconianone A, and in a total of 15 steps starting from γ‐hydroxy carvone. Mild reaction conditions for the subsequent α‐ketol rearrangement not only resulted in the herein proposed conversion of microsphaeropsisin B into periconianone C, but also in the conversion of microsphaeropsisin C into 4‐ epi ‐periconianone C." @default.
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- W2936736639 date "2019-04-17" @default.
- W2936736639 modified "2023-10-16" @default.
- W2936736639 title "The Furan Shuffling Hypothesis: A Biogenetic Proposal for Eremophilane Sesquiterpenoids" @default.
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- W2936736639 doi "https://doi.org/10.1002/anie.201901898" @default.
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