Matches in SemOpenAlex for { <https://semopenalex.org/work/W2936830837> ?p ?o ?g. }
- W2936830837 endingPage "6847" @default.
- W2936830837 startingPage "6843" @default.
- W2936830837 abstract "Converting elemental white phosphorus directly into organophosphorus or polyphosphorus is meaningful, challenging and attractive. The ate-complexes of aluminacyclopentadienes 1a,b react with P4 to afford selectively the cyclotetraphosphanes 2a,b featuring four newly formed P-C bonds and a planar square cyclo-P4 ring. Density functional theory calculations show that the conversion of tetrahedral P4 to planar cyclo-P4 moiety undergoes through an unexpected 1,1- P-insertion/Diels-Alder reaction/isomerization cascade process. The reaction of 2a with iodomethane or p-benzoquinone afforded the P-methylation product 3 and the metal-free cyclotetraphosphane 4, respectively. Interestingly, reduction of 4 generated the phospholyl anions 5 and 6 while treatment of 4 with iodomethane afforded the phospholyl cation 7." @default.
- W2936830837 created "2019-04-25" @default.
- W2936830837 creator A5025918204 @default.
- W2936830837 creator A5029642484 @default.
- W2936830837 creator A5035296514 @default.
- W2936830837 creator A5035801023 @default.
- W2936830837 creator A5046378812 @default.
- W2936830837 creator A5051879914 @default.
- W2936830837 creator A5075916046 @default.
- W2936830837 creator A5086223366 @default.
- W2936830837 date "2019-04-16" @default.
- W2936830837 modified "2023-09-25" @default.
- W2936830837 title "Direct Functionalization of White Phosphorus to Cyclotetraphosphanes: Selective Formation of Four P–C Bonds" @default.
- W2936830837 cites W1890814655 @default.
- W2936830837 cites W1964843655 @default.
- W2936830837 cites W1969657397 @default.
- W2936830837 cites W1975862747 @default.
- W2936830837 cites W1977075425 @default.
- W2936830837 cites W1994033404 @default.
- W2936830837 cites W1994431233 @default.
- W2936830837 cites W2006214162 @default.
- W2936830837 cites W2016112278 @default.
- W2936830837 cites W2016553560 @default.
- W2936830837 cites W2025238416 @default.
- W2936830837 cites W2025924067 @default.
- W2936830837 cites W2038871458 @default.
- W2936830837 cites W2044485440 @default.
- W2936830837 cites W2046298939 @default.
- W2936830837 cites W2048990493 @default.
- W2936830837 cites W2052208583 @default.
- W2936830837 cites W2054183877 @default.
- W2936830837 cites W2056946657 @default.
- W2936830837 cites W2060886373 @default.
- W2936830837 cites W2064668401 @default.
- W2936830837 cites W2069385563 @default.
- W2936830837 cites W2070327350 @default.
- W2936830837 cites W2082417077 @default.
- W2936830837 cites W2096245235 @default.
- W2936830837 cites W2111451692 @default.
- W2936830837 cites W2115641172 @default.
- W2936830837 cites W2118112288 @default.
- W2936830837 cites W2120258342 @default.
- W2936830837 cites W2122005358 @default.
- W2936830837 cites W2127400286 @default.
- W2936830837 cites W2133573517 @default.
- W2936830837 cites W2134856824 @default.
- W2936830837 cites W2137013960 @default.
- W2936830837 cites W2148856425 @default.
- W2936830837 cites W2149185910 @default.
- W2936830837 cites W2154263290 @default.
- W2936830837 cites W2155093834 @default.
- W2936830837 cites W2167101520 @default.
- W2936830837 cites W2168693083 @default.
- W2936830837 cites W2276962377 @default.
- W2936830837 cites W2301977075 @default.
- W2936830837 cites W2315470498 @default.
- W2936830837 cites W2422729348 @default.
- W2936830837 cites W2423280529 @default.
- W2936830837 cites W2521779573 @default.
- W2936830837 cites W2558686385 @default.
- W2936830837 cites W2579328165 @default.
- W2936830837 cites W2612089951 @default.
- W2936830837 cites W2612354169 @default.
- W2936830837 cites W2774761795 @default.
- W2936830837 cites W2809735358 @default.
- W2936830837 cites W2905226741 @default.
- W2936830837 cites W2917166011 @default.
- W2936830837 cites W2970108190 @default.
- W2936830837 doi "https://doi.org/10.1021/jacs.9b02628" @default.
- W2936830837 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30995028" @default.
- W2936830837 hasPublicationYear "2019" @default.
- W2936830837 type Work @default.
- W2936830837 sameAs 2936830837 @default.
- W2936830837 citedByCount "36" @default.
- W2936830837 countsByYear W29368308372019 @default.
- W2936830837 countsByYear W29368308372020 @default.
- W2936830837 countsByYear W29368308372021 @default.
- W2936830837 countsByYear W29368308372022 @default.
- W2936830837 countsByYear W29368308372023 @default.
- W2936830837 crossrefType "journal-article" @default.
- W2936830837 hasAuthorship W2936830837A5025918204 @default.
- W2936830837 hasAuthorship W2936830837A5029642484 @default.
- W2936830837 hasAuthorship W2936830837A5035296514 @default.
- W2936830837 hasAuthorship W2936830837A5035801023 @default.
- W2936830837 hasAuthorship W2936830837A5046378812 @default.
- W2936830837 hasAuthorship W2936830837A5051879914 @default.
- W2936830837 hasAuthorship W2936830837A5075916046 @default.
- W2936830837 hasAuthorship W2936830837A5086223366 @default.
- W2936830837 hasConcept C115537861 @default.
- W2936830837 hasConcept C126661725 @default.
- W2936830837 hasConcept C147789679 @default.
- W2936830837 hasConcept C155647269 @default.
- W2936830837 hasConcept C161790260 @default.
- W2936830837 hasConcept C178790620 @default.
- W2936830837 hasConcept C185592680 @default.
- W2936830837 hasConcept C2776568683 @default.
- W2936830837 hasConcept C2780378348 @default.
- W2936830837 hasConcept C2909421424 @default.