Matches in SemOpenAlex for { <https://semopenalex.org/work/W2936915777> ?p ?o ?g. }
- W2936915777 endingPage "3391" @default.
- W2936915777 startingPage "3387" @default.
- W2936915777 abstract "Chiral C2-symmetric phosphinic acids were designed based on sterically demanding and helical chiral perfluoroalkyl groups at the closest α-position advancing asymmetric reaction environment and catalytic activity. The perfluoroalkyl catalysts, [(CF3)2F2] and [(C2F5)2F2] phosphinic acids, were synthesized via a stereoselective addition/cyclization sequence of methyl phosphinate and deoxofluorination. These new classes of Brønsted acid catalysts were applied to an asymmetric Friedel–Crafts reaction to give up to 89% yield and 82% R-enantioselectivity, which is higher than those obtained with the parent phosphoric acid (42% and 55.5% S)." @default.
- W2936915777 created "2019-04-25" @default.
- W2936915777 creator A5066575852 @default.
- W2936915777 creator A5068399801 @default.
- W2936915777 creator A5069792177 @default.
- W2936915777 creator A5074281181 @default.
- W2936915777 date "2019-04-19" @default.
- W2936915777 modified "2023-10-16" @default.
- W2936915777 title "Design of Phosphinic Acid Catalysts with the Closest Stereogenicity at the α-Position: Synthesis and Application of α-Stereogenic Perfluoroalkyl Phosphinic Acid Catalysts" @default.
- W2936915777 cites W1520678632 @default.
- W2936915777 cites W1533603782 @default.
- W2936915777 cites W1967335182 @default.
- W2936915777 cites W1980896239 @default.
- W2936915777 cites W1990993700 @default.
- W2936915777 cites W1991060795 @default.
- W2936915777 cites W1992582121 @default.
- W2936915777 cites W1999739411 @default.
- W2936915777 cites W2008810249 @default.
- W2936915777 cites W2009233650 @default.
- W2936915777 cites W2010024344 @default.
- W2936915777 cites W2015608080 @default.
- W2936915777 cites W2016075951 @default.
- W2936915777 cites W2018465758 @default.
- W2936915777 cites W2022624426 @default.
- W2936915777 cites W2024120657 @default.
- W2936915777 cites W2032698433 @default.
- W2936915777 cites W2032951614 @default.
- W2936915777 cites W2052603216 @default.
- W2936915777 cites W2054114972 @default.
- W2936915777 cites W2057615451 @default.
- W2936915777 cites W2060231012 @default.
- W2936915777 cites W2067302659 @default.
- W2936915777 cites W2082972031 @default.
- W2936915777 cites W2085351645 @default.
- W2936915777 cites W2086138834 @default.
- W2936915777 cites W2091559409 @default.
- W2936915777 cites W2109116115 @default.
- W2936915777 cites W2120780345 @default.
- W2936915777 cites W2145841213 @default.
- W2936915777 cites W2148502720 @default.
- W2936915777 cites W2154934377 @default.
- W2936915777 cites W2166248750 @default.
- W2936915777 cites W2169174125 @default.
- W2936915777 cites W2173809998 @default.
- W2936915777 cites W2318522405 @default.
- W2936915777 cites W2320193430 @default.
- W2936915777 cites W2330628712 @default.
- W2936915777 cites W2333652590 @default.
- W2936915777 cites W2490681934 @default.
- W2936915777 cites W2794751464 @default.
- W2936915777 cites W2951521378 @default.
- W2936915777 cites W4211262099 @default.
- W2936915777 doi "https://doi.org/10.1021/acs.orglett.9b01131" @default.
- W2936915777 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/31002256" @default.
- W2936915777 hasPublicationYear "2019" @default.
- W2936915777 type Work @default.
- W2936915777 sameAs 2936915777 @default.
- W2936915777 citedByCount "8" @default.
- W2936915777 countsByYear W29369157772019 @default.
- W2936915777 countsByYear W29369157772021 @default.
- W2936915777 countsByYear W29369157772022 @default.
- W2936915777 crossrefType "journal-article" @default.
- W2936915777 hasAuthorship W2936915777A5066575852 @default.
- W2936915777 hasAuthorship W2936915777A5068399801 @default.
- W2936915777 hasAuthorship W2936915777A5069792177 @default.
- W2936915777 hasAuthorship W2936915777A5074281181 @default.
- W2936915777 hasConcept C134121241 @default.
- W2936915777 hasConcept C134195300 @default.
- W2936915777 hasConcept C146686406 @default.
- W2936915777 hasConcept C155647269 @default.
- W2936915777 hasConcept C161790260 @default.
- W2936915777 hasConcept C178790620 @default.
- W2936915777 hasConcept C181647583 @default.
- W2936915777 hasConcept C185592680 @default.
- W2936915777 hasConcept C191897082 @default.
- W2936915777 hasConcept C192562407 @default.
- W2936915777 hasConcept C201194858 @default.
- W2936915777 hasConcept C205474432 @default.
- W2936915777 hasConcept C21951064 @default.
- W2936915777 hasConcept C2776622989 @default.
- W2936915777 hasConcept C2780645613 @default.
- W2936915777 hasConcept C71240020 @default.
- W2936915777 hasConceptScore W2936915777C134121241 @default.
- W2936915777 hasConceptScore W2936915777C134195300 @default.
- W2936915777 hasConceptScore W2936915777C146686406 @default.
- W2936915777 hasConceptScore W2936915777C155647269 @default.
- W2936915777 hasConceptScore W2936915777C161790260 @default.
- W2936915777 hasConceptScore W2936915777C178790620 @default.
- W2936915777 hasConceptScore W2936915777C181647583 @default.
- W2936915777 hasConceptScore W2936915777C185592680 @default.
- W2936915777 hasConceptScore W2936915777C191897082 @default.
- W2936915777 hasConceptScore W2936915777C192562407 @default.
- W2936915777 hasConceptScore W2936915777C201194858 @default.
- W2936915777 hasConceptScore W2936915777C205474432 @default.
- W2936915777 hasConceptScore W2936915777C21951064 @default.
- W2936915777 hasConceptScore W2936915777C2776622989 @default.
- W2936915777 hasConceptScore W2936915777C2780645613 @default.
- W2936915777 hasConceptScore W2936915777C71240020 @default.