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• W2937040959 endingPage "8126" @default.
• W2937040959 startingPage "8118" @default.
• W2937040959 abstract "Abstract The guanidine 1,5,7‐triazabicyclo[4.4.0]dec‐5‐ene (TBD) and the substituted derivatives [TBD–SiR 2 ] + and TBD–BR 2 reacted with SO 2 to give different FLP–SO 2 adducts. Molecular structures, elucidated by X‐ray diffraction, showed some structural similarities with the analogous CO 2 adducts. Thermodynamic stabilities were both experimentally evidenced and computed through DFT calculations. The underlying parameters governing the relative stabilities of the different SO 2 and CO 2 adducts were discussed from a theoretical standpoint, with a focus on the influence of the Lewis acidic moiety." @default.
• W2937040959 created "2019-04-25" @default.
• W2937040959 creator A5021299818 @default.
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• W2937040959 creator A5078466046 @default.
• W2937040959 creator A5079733641 @default.
• W2937040959 creator A5089982300 @default.
• W2937040959 date "2019-05-17" @default.
• W2937040959 modified "2023-10-10" @default.
• W2937040959 title "Activation of SO ₂ by N/Si ⁺ and N/B Frustrated Lewis Pairs: Experimental and Theoretical Comparison with CO ₂ Activation" @default.
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• W2937040959 doi "https://doi.org/10.1002/chem.201901088" @default.
• W2937040959 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30968976" @default.

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