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- W2937150932 abstract "Luminmycin A, a natural proteasome inhibitor transcripted by a silent gene cluster from Photorhabdus luminescens , belongs to the compound family of the syrbactins and is structurally closely related to the glidobactins. Key step for the synthesis of the 12‐membered cyclopeptide ring is an intramolecular Horner–Wadsworth–Emmons reaction, while the double unsaturated fatty acid side chain can be obtained via phosphane‐catalyzed isomerization of a corresponding acetylenic fatty acid ester." @default.
- W2937150932 created "2019-04-25" @default.
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- W2937150932 date "2019-05-20" @default.
- W2937150932 modified "2023-09-25" @default.
- W2937150932 title "Total Synthesis of Luminmycin A, a Cryptic Natural Product from Photorhabdus Luminescens" @default.
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- W2937150932 doi "https://doi.org/10.1002/ejoc.201900460" @default.
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