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- W2937191847 abstract "5-Thio-D-ribose has been synthesised from methyl 2,3-isopropylidene-5-O-toluene-p-sulphonyl-β-D-ribofuranoside. Two crystalline forms of the sugar having different signs of optical rotation were obtained although, more commonly, they co-crystallised. The absence of an SH absorption in their infrared spectra indicates the dextrorotatory and laevorotatory forms to be the α-D-pyranose and β-D-pyranose isomers, respectively. Their mutarotation curves are simple, in contrast to that of β-D-ribopyranose, suggesting the absence of furanoid forms in the equilibria. Methyl 5-thio-α- and β-D-ribopyranosides are the major products of the Fischer reaction of the sugar with methanolic hydrogen chloride. The two thiopyranosides undergo acidic hydrolysis more readily than the corresponding methyl α- and β-D-ribopyranosides." @default.
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- W2937191847 date "1967-03-01" @default.
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- W2937191847 title "5-thio-D-ribopyranose" @default.
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- W2937191847 doi "https://doi.org/10.1016/s0008-6215(00)81145-3" @default.
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