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- W2937360054 endingPage "5282" @default.
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- W2937360054 abstract "We report herein the exploitment of the partially fluorinated trifluoroethyl as precatalyst ligands in nickel-catalyzed Suzuki-type alkylation and fluoroalkylation coupling reactions. Compared with the [L n NiII(aryl)(X)] precatalysts, the unique characters of bis-trifluoroethyl ligands imparted precatalyst [(bipy)Ni(CH2CF3)2] with bench-top stability, good solubilities in organic media and interesting catalytic activities. Preliminary mechanistic studies reveal that an eliminative extrusion of a vinylidene difluoride (VDF, CH2[double bond, length as m-dash]CF2) mask from [(bipy)Ni(CH2CF3)2] is a critical step for the initiation of a catalytic reaction." @default.
- W2937360054 created "2019-04-25" @default.
- W2937360054 creator A5001233354 @default.
- W2937360054 creator A5009377050 @default.
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- W2937360054 creator A5035567664 @default.
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- W2937360054 creator A5048936740 @default.
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- W2937360054 creator A5075913121 @default.
- W2937360054 creator A5084146813 @default.
- W2937360054 date "2019-01-01" @default.
- W2937360054 modified "2023-10-12" @default.
- W2937360054 title "Exploiting the trifluoroethyl group as a precatalyst ligand in nickel-catalyzed Suzuki-type alkylations" @default.
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