FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2937948436> ?p ?o ?g. }

• W2937948436 endingPage "6529" @default.
• W2937948436 startingPage "6521" @default.
• W2937948436 abstract "In this study, we show that equilibrium pH can be obtained for any specified fluid with any number of buffers and dissociations. This is done by root finding in the equation for charge balance. We demonstrate that this equation is monotonic in proton concentration for conceivable buffers. We show that the total charge on any buffer is a function of only the total buffer concentration and pH, given the thermodynamic dissociation constants. Using the Davies' equation as a placeholder for single-ion activity coefficients as a function of charge and ionic strength, we develop an iterative algorithm, whereby the apparent dissociation constants are updated from the thermodynamic dissociation constants, and from this, the equilibrium is also identified in the nonideal state. We show how this algebra leads to guaranteed conservation of both thermodynamic dissociation constants and total buffer concentrations because the distribution of buffer species is fixed by the updated dissociation constants, actual pH, and total buffer concentration. Strong ions are assumed to contribute fixed charges. In order to concentrate on the process of modeling the equilibrium pH alone, this algorithm is examined against a series of theoretical results in which the Davies' equation was given the same status. However, a large sample of clinical pH measurements is also examined. To enhance the practical utility, CO2 and albumin are present as the default condition. We developed ABCharge, a package in R, an open source language. The main function returns pH, activity coefficients, buffer species distribution, ionic strength, and charge balance for both the ideal and nonideal cases, for any mixture of any buffers with any number of known thermodynamic dissociation constants. Our algorithm can be updated if a more reliable and practical assessment of single-ion activities becomes available. Can Stock Photo/miceking." @default.
• W2937948436 created "2019-04-25" @default.
• W2937948436 creator A5021022035 @default.
• W2937948436 creator A5054338861 @default.
• W2937948436 date "2019-04-09" @default.
• W2937948436 modified "2023-09-28" @default.
• W2937948436 title "Modeling Acid–Base by Minimizing Charge-Balance" @default.
• W2937948436 cites W1794873186 @default.
• W2937948436 cites W1970070688 @default.
• W2937948436 cites W1994095596 @default.
• W2937948436 cites W1998925054 @default.
• W2937948436 cites W2013904373 @default.
• W2937948436 cites W2017321732 @default.
• W2937948436 cites W2026186992 @default.
• W2937948436 cites W2036543035 @default.
• W2937948436 cites W2047916395 @default.
• W2937948436 cites W2058093303 @default.
• W2937948436 cites W2066390112 @default.
• W2937948436 cites W2083582681 @default.
• W2937948436 cites W2090793893 @default.
• W2937948436 cites W2142073124 @default.
• W2937948436 cites W2148195475 @default.
• W2937948436 cites W2148523763 @default.
• W2937948436 cites W2250853480 @default.
• W2937948436 cites W2315337848 @default.
• W2937948436 cites W2328023710 @default.
• W2937948436 cites W2518861649 @default.
• W2937948436 cites W2559953557 @default.
• W2937948436 cites W2562944093 @default.
• W2937948436 cites W2783019859 @default.
• W2937948436 cites W2783559884 @default.
• W2937948436 cites W2803631979 @default.
• W2937948436 cites W2900975103 @default.
• W2937948436 cites W2910923506 @default.
• W2937948436 cites W3142417238 @default.
• W2937948436 cites W3146402314 @default.
• W2937948436 cites W4253317845 @default.
• W2937948436 cites W99939816 @default.
• W2937948436 doi "https://doi.org/10.1021/acsomega.9b00270" @default.
• W2937948436 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/6648237" @default.
• W2937948436 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/31459783" @default.
• W2937948436 hasPublicationYear "2019" @default.
• W2937948436 type Work @default.
• W2937948436 sameAs 2937948436 @default.
• W2937948436 citedByCount "6" @default.
• W2937948436 countsByYear W29379484362021 @default.
• W2937948436 countsByYear W29379484362022 @default.
• W2937948436 countsByYear W29379484362023 @default.
• W2937948436 crossrefType "journal-article" @default.
• W2937948436 hasAuthorship W2937948436A5021022035 @default.
• W2937948436 hasAuthorship W2937948436A5054338861 @default.
• W2937948436 hasBestOaLocation W29379484361 @default.
• W2937948436 hasConcept C102931765 @default.
• W2937948436 hasConcept C121332964 @default.
• W2937948436 hasConcept C134306372 @default.
• W2937948436 hasConcept C145148216 @default.
• W2937948436 hasConcept C147789679 @default.
• W2937948436 hasConcept C170493617 @default.
• W2937948436 hasConcept C170961132 @default.
• W2937948436 hasConcept C178790620 @default.
• W2937948436 hasConcept C184651966 @default.
• W2937948436 hasConcept C185592680 @default.
• W2937948436 hasConcept C187428577 @default.
• W2937948436 hasConcept C2182769 @default.
• W2937948436 hasConcept C2778117296 @default.
• W2937948436 hasConcept C33923547 @default.
• W2937948436 hasConcept C55493867 @default.
• W2937948436 hasConcept C72169020 @default.
• W2937948436 hasConcept C74998103 @default.
• W2937948436 hasConcept C97355855 @default.
• W2937948436 hasConceptScore W2937948436C102931765 @default.
• W2937948436 hasConceptScore W2937948436C121332964 @default.
• W2937948436 hasConceptScore W2937948436C134306372 @default.
• W2937948436 hasConceptScore W2937948436C145148216 @default.
• W2937948436 hasConceptScore W2937948436C147789679 @default.
• W2937948436 hasConceptScore W2937948436C170493617 @default.
• W2937948436 hasConceptScore W2937948436C170961132 @default.
• W2937948436 hasConceptScore W2937948436C178790620 @default.
• W2937948436 hasConceptScore W2937948436C184651966 @default.
• W2937948436 hasConceptScore W2937948436C185592680 @default.
• W2937948436 hasConceptScore W2937948436C187428577 @default.
• W2937948436 hasConceptScore W2937948436C2182769 @default.
• W2937948436 hasConceptScore W2937948436C2778117296 @default.
• W2937948436 hasConceptScore W2937948436C33923547 @default.
• W2937948436 hasConceptScore W2937948436C55493867 @default.
• W2937948436 hasConceptScore W2937948436C72169020 @default.
• W2937948436 hasConceptScore W2937948436C74998103 @default.
• W2937948436 hasConceptScore W2937948436C97355855 @default.
• W2937948436 hasIssue "4" @default.
• W2937948436 hasLocation W29379484361 @default.
• W2937948436 hasLocation W29379484362 @default.
• W2937948436 hasLocation W29379484363 @default.
• W2937948436 hasLocation W29379484364 @default.
• W2937948436 hasLocation W29379484365 @default.
• W2937948436 hasOpenAccess W2937948436 @default.
• W2937948436 hasPrimaryLocation W29379484361 @default.
• W2937948436 hasRelatedWork W1707155556 @default.
• W2937948436 hasRelatedWork W1972678568 @default.

• next