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- W2938373025 abstract "Carbene polymerization provides polyolefins that cannot be readily prepared from olefin monomers; however, controlled and living carbene polymerization has been a long-standing challenge. Here we report a new class of initiators, (π-allyl)palladium carboxylate dimers, which polymerize ethyl diazoacetate, a carbene precursor in a controlled and quasi-living manner, with nearly quantitative yields, degrees of polymerization >100, molecular weight dispersities 1.2-1.4, and well-defined, diversifiable chain ends. This method also provides block copolycarbenes that undergo microphase segregation. Experimental and theoretical mechanistic analysis supports a new dinuclear mechanism for this process." @default.
- W2938373025 created "2019-04-25" @default.
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- W2938373025 date "2019-04-09" @default.
- W2938373025 modified "2023-10-13" @default.
- W2938373025 title "A Dinuclear Mechanism Implicated in Controlled Carbene Polymerization" @default.
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- W2938373025 doi "https://doi.org/10.1021/jacs.9b01532" @default.
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