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• W2938473612 abstract "Feeding studies indicate a possible synthetic pattern for the N-terminal cis-aminocyclopentane carboxylic acid (ACPC) and suggest an unusual source of the high-carbon sugar skeleton of amipurimycin (APM). The biosynthetic gene cluster of APM was identified and confirmed by in vivo experiments. A C9 core intermediate was discovered from null mutants of ACPC pathway, and an ATP-grasp enzyme (ApmA8) was reconstituted in vitro for ACPC loading. Our observations allow a first proposal of the APM biosynthetic pathway." @default.
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• W2938473612 date "2019-04-16" @default.
• W2938473612 modified "2023-10-11" @default.
• W2938473612 title "Identification of the Amipurimycin Gene Cluster Yields Insight into the Biosynthesis of C9 Sugar Nucleoside Antibiotics" @default.
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• W2938473612 doi "https://doi.org/10.1021/acs.orglett.9b00840" @default.
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