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• W2938559629 abstract "Site-selective introduction of a sulfur group into aromatic compounds is essential and useful in organic, material, and pharmaceutical chemistry. A palladium/norbornene-catalyzed chemoselective ortho thiolation of aryl halides was reported. The selectivity of reductive elimination for C(Ar)-SR bond formation was well controlled by tuning the ancillary ligand in the aryl-NBE palladacycle Pd(IV) intermediate. The reaction showcased good substrate scope: both S-alkyl and S-aryl thiosulfonates were compatible." @default.
• W2938559629 created "2019-04-25" @default.
• W2938559629 creator A5014950631 @default.
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• W2938559629 date "2019-04-12" @default.
• W2938559629 modified "2023-10-10" @default.
• W2938559629 title "Selective <i>Ortho</i> Thiolation Enabled by Tuning the Ancillary Ligand in Palladium/Norbornene Catalysis" @default.
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• W2938559629 doi "https://doi.org/10.1021/acs.orglett.9b00923" @default.
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• W2938559629 hasPublicationYear "2019" @default.
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