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- W2938632425 abstract "The internal cavity size of a metallosupramolecular assembly can be tuned by thoughtful design of the ligand. This work reports the introduction of imidazo[1,5-a]pyridine scaffolds in place of the conventional imidazol-2-ylidene moieties, which resulted in new molecular containers bearing significantly enlarged cavities. The new hexacarbene metal assemblies can easily accommodate a dimethylsulfoxide molecule as a molecular guest. This is the first study of a unique “host–guest” system featuring an organometallic cylinder-like cage exclusively derived from poly-NHC ligands. More information can be found in the Full Paper by Y.-F. Han et al. on page 5472." @default.
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- W2938632425 date "2019-03-15" @default.
- W2938632425 modified "2023-09-27" @default.
- W2938632425 title "Cover Feature: Synthesis, Characterization, and Properties of Organometallic Molecular Cylinders Bearing Bulky Imidazo[1,5‐ a ]pyridine‐Based N‐Heterocyclic Carbene Ligands (Chem. Eur. J. 21/2019)" @default.
- W2938632425 doi "https://doi.org/10.1002/chem.201901056" @default.
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